List of Peer-Reviewed Publications

2026

Structure-Function Mapping of Host Defense Peptide Mimics Reveals Strategies for Antibacterial Activity and Eradication of Mature Bacterial Biofilms. Green Chem. 2026, 尚未分配卷期.†

Miao, B. L.; Wang, Y. S.; Liu, Y.; Da, G. H.; Wang, Y.; Chen, X.; Shao, Z. Z. Ultrathin, Flexible, and Multifunctional Silk Fibroin-Ag Functional Engineered Membranes for Integrated Separation, Treatment, and Detection of Water Pollutants. ACS Appl. Mater. Interfaces 2026, 18 (1), 2795–2806. https://doi.org/10.1021/acsami.5c22309

Zheng, X.; Gao, W. L.; Liu, W.-Q.; Zhang, Y. F.; Huang, S. H.; Ji, X. Y.; Lu, Y. C.; Liu, Y. F.; Ling, S. J.; Li, J. Reconstituting Transcription–Translation-Coupled DNA Replication within Complex in Vitro Biological Systems. Nat. Commun. 2026, 17, 351. https://doi.org/10.1038/s41467-025-56160-x

2025

Yang, S.; Yang, Y. H.; Huang, C.; Bai, R. N.; Cao, L. T.; Ren, J.; Ling, S. J. Physics-Informed Graph Neural Networks for Predicting Deformation in Disordered Fibrous Materials. Nano Lett. 2025, 26, 205-213. https://doi.org/10.1021/acs.nanolett.5c04895

Liu, Z. Y.; Yang, S.; Cao, L. T.; Ren, J.; Yao, J. R.; Chen, X.; Shao, Z. Z.; Ling, S. J. Biomimetic Hierarchical Molecular Assembly of Silk-Hydroxyapatite Composites for Near-Native Bone Regeneration. Adv. Funct. Mater. 2025, 2524279. https://doi.org/10.1002/adfm.202524279

Song, Y. H.; Li, J.; Li, X. Y.; Liu, H. M.; Sha, Z.; Ge, Y. R.; Chen, X.; Shao, Z. Z.; Fei, X.; Zhu, M. F. Dual In Situ Integration for Braided Silk Fibers Enabling Multifunctional Bioactive Sutures. Interdiscip. Mater. 2025, 4 (6), 927–940. https://doi.org/10.1002/idm2.70025

Xiao, M. L.; Sun, L. Y.; Fu, H.; Yang, W. H.; Yao, J. R.; Shao, Z. Z.; Ling, S. J.; Zhao, B. J.; Chen, X. An Expandable Silk Fibroin/Montmorillonite Porous Scaffolds Based on Clinical Dual Hemostasis Concept and Its Application in Bone Regeneration of Tooth Extraction Sockets with Coagulation Disorders. Adv. Healthcare Mater. 2025, 2500930. https://doi.org/10.1002/adhm.202500930

Lin, Q. R.; Liu, Y.; Li, Y. M.; Li, L. J. Z.; Vollrath, F.; Ji, M. B.; Shao, Z. Z. From Snapshot to Movie: Visualizing Native Silk Spinning Defines the Paradigm for Bio-Inspired Spinning. Adv. Funct. Mater. 2025, 2420175. https://doi.org/10.1002/adfm.202420175

Yang, S.; Peng, R. X.; Cao, L. T.; Ren, J.; Yao, J. R.; Chen, X.; Shao, Z. Z.; Ling, S. J. Hierarchical Silk Fibril Networks Exhibit Structure Dependent Mechanical Performance. Adv. Funct. Mater. 2025, e25857. https://doi.org/10.1002/adfm.202425857

Zhang, Y. Y.; Ling, S. J.; Chen, W. S.; Buehler, M. J.; Kaplan, D. L. Exploring Nature's Toolbox: The Role of Biopolymers in Sustainable Materials Science. Adv. Mater. 2025, 37 (22), 2507822. https://doi.org/10.1002/adma.202507822

Ye, C.; Zhang, H.; Yang, Y. H.; Shan, Y. C.; Fu, J. H.; Gao, W. L.; Ren, J.; Cao, L. T.; Ling, S. J. Sustainable Silk Fibroin Ionic Touch Screens for Flexible Biodegradable Electronics with Integrated AI and IoT Functionality. Adv. Mater. 2025, 37 (22), 2412972. https://doi.org/10.1002/adma.202412972

Jiang, C. H.; Fu, J. H.; Zhang, H.; Hua, Y. J.; Cao, L. T.; Ren, J.; Zhou, M. L.; Jiang, F.; Jiang, X. Q.; Ling, S. J. Self-Reinforcing Ionogel Bioadhesive Interface for Robust Integration and Monitoring of Bioelectronic Devices with Hard Tissues. Adv. Mater. 2025, 37 (22), 2413028. https://doi.org/10.1002/adma.202413028

Li, C. F.; Sun, Y. J.; Li, Y.; Jiao, C. L.; Fu, X. T.; Zhou, X.; Li, Z. H.; Ling, S. J.; Ye, D. D.; Zheng, K. Biomimetic Interface Engineering Approach for Universal Toughening of Rigid Fibers. Adv. Funct. Mater. 2025, 35 (31), 2501380. https://doi.org/10.1002/adfm.202501380

Li, Z. J.; Dong, W. P.; Ren, J.; Gao, W. L.; Cao, L. T.; Gu, Y.; Ling, S. J. Mechanically Trained Calcium Alginate Ionic Hydrogels for Enhanced Abdominal Wall Defect Repair. Adv. Funct. Mater. 2025, 35 (22), 2419151. https://doi.org/10.1002/adfm.202419151

Yang, Y. H.; Bai, R. N.; Gao, W. L.; Cao, L. T.; Ren, J.; Shao, Z. Z.; Ling, S. J. Optimizing Biomimetic 3D Disordered Fibrous Network Structures for Lightweight, High-Strength Materials via Deep Reinforcement Learning. Adv. Sci. 2025, 12 (11), 2413293. https://doi.org/10.1002/advs.202413293

Gao, W. L.; Yu, M. F.; Cao, L. T.; Wen, P.; Sun, Y.; Ren, J.; Ling, S. J. Identification and Screening of Trace and Multityped Solvents Using Transpiration-Driven Electrokinetic Generation Principle. Nano Lett. 2025, 25 (6), 2396–2403. https://doi.org/10.1021/acs.nanolett.5c00152

Zhu, J. W.; Meng, Y. R.; Gao, W. L.; Yang, S.; Zhu, W. J.; Ji, X. Y.; Zhai, X. P.; Liu, W.-Q.; Luo, Y.; Ling, S. J.; Li, J.; Liu, Y. F. AI-Driven High-Throughput Droplet Screening of Cell-Free Gene Expression. Nat. Commun. 2025, 16, 2720. https://doi.org/10.1038/s41467-025-57967-2

Zhang, J. H.; Gao, W. L.; Wang, Y.; Shan, Y. C.; Dong, S. J.; Cao, L. T.; Li, Z. J.; Zhang, H. T.; Ren, J.; Ling, S. J. Spider Web Like Artificial Network for Smart Capture. Small 2025, 21, 2501687. https://doi.org/10.1002/smll.202501687

Yang, K.; Zhang, J. W.; Zhang, C.; Guan, J.; Ling, S. J.; Shao, Z. Z. Hierarchical Design of Silkworm Silk for Functional Composites. Chem. Soc. Rev. 2025, 54 (10), 4973–5020. https://doi.org/10.1039/D4CS00939H

Liu, Z. Y.; Tilieke, M.; Zhou, Y.; Ming, M. D.; Zhang, H. T.; Chen, L.; Zheng, R.; Jie, Y. S.; Shu, X.; Guan, J.; Ling, S. J.; Chen, X.; Shao, Z. Z. Calcium Polyphosphate Endows Silk Fibroin Hydrogels with Enhanced Osteogenesis for Bone Function Restoration. J. Mater. Chem. B 2025, 13 (33), 10331–10342. https://doi.org/10.1039/D5TB01315A

Fu, Y.; Li, L. J. Z.; Ye, C.; Cao, L. T.; Yao, J. R.; Chen, X.; Ling, S. J.; Shao, Z. Z. Deep Eutectic Solvent Infused Silk Fibroin Gels for Flexible Touch Sensing. J. Mater. Chem. C 2025, 13 (36), 18894–18904. https://doi.org/10.1039/D5TC02134K

Xiao, M. L.; Sun, L. Y.; Fu, H.; Yang, W. H.; Yao, J. R.; Shao, Z. Z.; Ling, S. J.; Zhao, B. J.; Chen, X. Controllable Fabrication of Silk Fibroin Porous Scaffolds and Their Regulation on Cellular Behaviours. J. Mater. Chem. B 2025, 13 (18), 5453–5465. https://doi.org/10.1039/D5TB00148J

Xiao, M. L.; Sun, L. Y.; Wu, K.; Ding, Y. Q.; Wang, P. P.; Mu, C. C.; Yao, J. R.; Shao, Z. Z.; Zhao, B. J.; Chen, X. A Sequential Drug Delivery System Based on Silk Fibroin Scaffold for Effective Cartilage Repair. Bioact. Mater. 2025, 49, 255–270. https://doi.org/10.1016/j.bioactmat.2025.03.018

Xiao, M. L.; Liu, W.; Chen, L.; Zhao, B. J.; Sun, L. Y.; Yang, W. H.; Yao, J. R.; Shao, Z. Z.; Ling, S. J.; Chen, X. Hemostatic, Antimicrobial, and Thixotropic Hydrogels Based on Natural Silk Nanofibril/Halloysite Nanotube/Extracellular Vesicle Hybrids. Adv. Mater. Technol. 2025, 10 (13), 2500592. https://doi.org/10.1002/admt.202500592

Tilieke, M.; Shu, X.; Chen, L.; Jie, Y. S.; Zheng, R.; Zhang, Z.; Numata, K.; Guan, J.; Shao, Z. Z. Rapid UV-Induced and Robust Methacrylated Silk Fibroin Reinforced Polyacrylamide-Based Triple-Crosslinked Hydrogels. Int. J. Biol. Macromol. 2025, 318 (4), 145266. https://doi.org/10.1016/j.ijbiomac.2025.145266

Lu, X.; Lin, Z. D.; Li, L. J. Z.; Xu, G. Y.; Li, D. C.; Gong, Z. Y.; Wu, J. D.; Gao, T.; Guo, X. Y.; Xu, C. P.; Xia, X. L.; Lyu, F.; Zou, F.; Jiang, J. Y.; Shao, Z. Z.; Ma, X. S.; Wang, H. L.; Song, J. Exosome-Loaded Methacrylated Silk Fibroin Hydrogel Delays Intervertebral Disc Degeneration by DKK2-Mediated Mitochondrial Unfolded Protein Response. Chem. Eng. J. 2025, 511, 160359. https://doi.org/10.1016/j.cej.2025.160359

Zhong, N. P.; Du, L. X.; Bai, Y. L.; Chen, Z. C.; Cai, L. H.; Shao, Z. Z.; Zhao, X. A Novel 3D-Printed Silk Fibroin/Hydroxypropyl Methyl Cellulose Scaffold with Good Biocompatibility and Controllable Degradation in Vivo. J. Biomater. Appl. 2025, 40 (5), 565–579. https://doi.org/10.1177/08853282251314019

Ma, Y. Q.; Xia, S. C.; Hu, A. N.; Zhang, Q. Y.; Shao, Z. Z.; Tian, B.; Lin, Q. R. Ultrabright Contrast Agents with Synergistic Raman Enhancements for Precise Intraoperative Imaging and Photothermal Ablation of Orthotopic Tumor Models. J. Nanobiotechnol. 2025, 23 (1), 23. https://doi.org/10.1186/s12951-025-03099-2

Shan, Y. C.; Cao, L. T.; Wang, Y.; Ren, J.; Huang, C.; Gao, W. L.; Ling, S. J. AI-Driven Generative and Reinforcement Learning for Mechanical Optimization of 2D Patterned Hollow Structures. Mater. Futures 2025, 4, 035001. https://doi.org/10.1088/2752-5724/adb9f9

Yang, Y. H.; Cao, L. T.; Ren, J.; Gao, W. L.; Ling, S. J. Artificial Intelligence for Fibrous Network Design and Mechanics. AI Sci. 2025, 1, 012001. https://doi.org/10.1088/2977-3466/ada871

Yang, S.; Ren, J.; Gao, W. L.; Cao, L. T.; Ling, S. J. Artificial Intelligence-Driven Approaches for the Rational Design of Peptides with Predictable Aggregation Propensity. npj Soft Matter 2025, 1, 4. https://doi.org/10.1038/s44397-025-00004-4

Gao, W. L.; Bai, R. N.; Ling, S. J. Artificial Intelligence-Enabled Cellular Agriculture: Multiscale Modeling, Process Optimization, and Future Directions. Trends Food Sci. Technol. 2025, 163, 105193. https://doi.org/10.1016/j.tifs.2025.105193

于梦菲; 高文丽; 任婧; 曹雷涛; 彭若铉; 凌盛杰. 摩擦纳米发电机用皮芯结构纤维的制备及其性能. 纺织学报 2025, 46 (5), 1–9. https://doi.org/10.13475/j.fzxb.20240801401

2024

Chen, Q. L.; Yang, S.; Wang, Y.; Peng, R. X.; Gao, W. L.; Cao, L. T.; Yao, J. R.; Shao, Z. Z.; Chen, X.; Ling, S. J. Flexible Photoacoustic Device Integrating Electroluminescence, Piezoelectric Vibration, and Pressure Sensing. ACS Appl. Mater. Interfaces 2024, 16 (50), 69973–69983. https://doi.org/10.1021/acsami.4c16597

Liu, Y.; Song, Y. F.; Wang, J.; Shao, Z. Z. Elevating Postinjection Stability in Silk Nanofibril Hydrogels to Prevent Intervertebral Disc Degeneration. Biomacromolecules 2024, 25 (12), 7828–7837. https://doi.org/10.1021/acs.biomac.4c01118

Chen, Q. L.; Wu, K.; Yao, J. R.; Shao, Z. Z.; Chen, X. Adhesive Silk Fibroin/Magnesium Composite Films and Their Application for Removable Wound Dressing. Biomater. Sci. 2024, 13 (3), 694–706. https://doi.org/10.1039/D4BM01411A

Chen, X. Y.; Wen, H. J.; Yao, J. R.; Chen, X.; Wang, Y.; Shao, Z. Z. Highly Water-Dispersible Spiropyran-Octapeptide Supramolecules: Efficient, Multi-processable, and Versatile Photoswitches for Time-Dependent Dual-Mode Encryption. Adv. Funct. Mater. 2024, 35 (4), 2414865. https://doi.org/10.1002/adfm.202414865

Liang, Q.; Xu, Q.; Yang, G. W.; Xu, Y. T.; Huang, H. X.; Hou, Z. S.; Shao, Z. Z.; Wang, M.; Sun, Y. L. Femtosecond Laser Direct Writing Bombyx mori Sericin-Based Nanocomposites into Intrinsically Soft Wearable Micro-/Nano-Electronics. Nanoscale 2024, 16 (42), 19780–19791. https://doi.org/10.1039/D4NR02442G

Bi, Y. F.; Chen, X. Y.; Luo, F. Y.; Wang, X. H.; Chen, X.; Yao, J. R.; Shao, Z. Z. Magnetic Silk Fibroin Nanospheres Loaded with Amphiphilic Polypeptides and Antibiotics for Biofilm Eradication. Biomater. Sci. 2024, 12 (20), 5337–5348. https://doi.org/10.1039/D4BM00940A

Fu, Y.; Lin, Q. R.; Lan, R. Q.; Shao, Z. Z. Ultra-Strong Protein-Based Hydrogels via Promoting Intermolecular Entanglement of the Amorphous Region. Small 2024, 20 (48), 2403058. https://doi.org/10.1002/smll.202403058

Wang, Z. X.; Yin, X. Y.; Zhuang, C. Y.; Wu, K.; Wang, H. R.; Shao, Z. Z.; Tian, B.; Lin, H. Injectable Regenerated Silk Fibroin Micro/Nanosphere with Enhanced Permeability and Stability for Osteoarthritis Therapy. Small 2024, 20 (46), 2405049. https://doi.org/10.1002/smll.202405049

Sun, L. Y.; Xiao, M. L.; Chen, L.; Ni, L. Y.; Chen, X. X.; Zhang, L. N.; Yao, J. R.; Shao, Z. Z.; Zhao, B. J.; Chen, X.; Liu, Y. H. Enhanced Tissue Regeneration Through Immunomodulatory Extracellular Vesicles Encapsulated in Diversified Silk-Based Injectable Hydrogels. Adv. Healthcare Mater. 2024, 13 (28), 2401637. https://doi.org/10.1002/adhm.202401637

Chen, L.; Liu, W.; Xiao, M. L.; Sun, L. Y.; Chen, X. X.; Ni, L. Y.; Yao, J. R.; Shao, Z. Z.; Zhao, B. J.; Chen, X. Super Stable Silk Nanofibrils Prepared by an Improved Exfoliation Method and Their Related Applications. Adv. Mater. Technol. 2024, 9 (20), 2400608. https://doi.org/10.1002/admt.202400608

Gu, K.; Tong, Y. X.; Mi, R. X.; Leng, S. Y.; Yao, J. R.; Huang, H. W.; Chen, X.; Shao, Z. Z. The Production of Soluble Regenerated Silk Fibroin Powder with High Molecular Weight and Silk Protein-Based Materials. Giant 2024, 19, 100316. https://doi.org/10.1016/j.giant.2024.100316

Wang, Y.; Gao, W. L.; Chen, Q. L.; Ren, J.; Chen, X.; Li, J.; Shao, Z. Z.; Ling, S. J. Mechanically Modulable and Human-Machine Interactive Luminescent Fiber Display Platforms. MRS Bull. 2024, 49 (8), 802–816. https://doi.org/10.1557/s43577-024-00738-5

Gao, H.; Chen, N.; Sun, L. Y.; Sheng, D. D.; Zhong, Y. T.; Huang, M. R.; Yu, C. X.; Yang, X.; Hao, Y. F.; Chen, S. Y.; Shao, Z. Z.; Chen, J. Time-Programmed Release of Curcumin and Zn²⁺ from Multi-Layered RSF Coating Modified PET Graft for Improvement of Graft-Host Integration. Int. J. Biol. Macromol. 2024, 272, 132879. https://doi.org/10.1016/j.ijbiomac.2024.132879

Xiao, M. L.; Yao, J. R.; Shao, Z. Z.; Chen, X. Silk-Based 3D Porous Scaffolds for Tissue Engineering. ACS Biomater. Sci. Eng. 2024, 10 (5), 2827–2840. https://doi.org/10.1021/acsbiomaterials.4c00373

Zhou, B.; Luo, F. Y.; Liu, Y.; Shao, Z. Z. Engineering a High-Strength and Superior-Electrolyte Wettability Silk Fibroin-Based Gel Interface Achieving Dendrite-Free Zn Anode. ACS Appl. Mater. Interfaces 2024, 16 (15), 18927–18936. https://doi.org/10.1021/acsami.4c01168

Miao, B. L.; Wang, Y. S.; Liu, Y.; Da, G. H.; Wang, Y.; Chen, X.; Shao, Z. Z. An Interfacial-Assembled Self-Supporting Nanofilm Induced by Strong Intermolecular Interaction between Silk Fibroin and Lysozyme. Adv. Funct. Mater. 2024, 34 (16), 2312324. https://doi.org/10.1002/adfm.202312324

Yang, G. W.; Chen, X. Y.; Shi, W. J.; Chen, N.; Liu, Y.; Zhang, B.; Shao, Z. Z. Facile Preparation of a Photo-Cross-Linked Silk Fibroin-Poly Ionic Liquid Hydrogel with Antifreezing and Ion Conductive Properties. ACS Appl. Mater. Interfaces 2024, 16 (1), 1543–1552. https://doi.org/10.1021/acsami.3c16014

Li, X. Y.; Chen, N.; Yang, G. W.; Shao, Z. Z. Design and Preparation of Antifreeze Silk-Based Bioadhesive. Acta Polym. Sin. 2024, 55 (11), 1463–1475. https://doi.org/10.11777/j.issn1000-3304.2024.24093

Jin, F.; Guan, Z. R.; Zhang, J. H.; Qu, Z. G.; Ling, S. J.; Cao, L. T.; Ren, J.; Peng, R. X. Silk Fibroin Seed Coatings: Towards Sustainable Seed Protection and Enhanced Growth. Polymers 2024, 16 (23), 3281. https://doi.org/10.3390/polym16233281

Wu, C. C.; Duan, Y.; Yu, L. T.; Hu, Y.; Zhao, C. X.; Ji, C. W.; Guo, X. D.; Zhang, S.; Dai, X. K.; Ma, P. Y.; Wang, Q.; Ling, S. J.; Yang, X. X.; Dai, Q. In-Situ Observation of Silk Nanofibril Assembly via Graphene Plasmonic Infrared Sensor. Nat. Commun. 2024, 15, 4643. https://doi.org/10.1038/s41467-024-48845-2

Zhou, W. M.; Sun, S. J.; Zhang, Y. T.; Wang, S. Q.; Zhang, S.; Ling, S. J.; Mei, C. T.; Pan, M. Z. Dynamic Organic-Inorganic Hybrid Network for Self-Healing and Self-Powered Fire Hazard Sensor. Chem. Eng. J. 2024, 484, 149331. https://doi.org/10.1016/j.cej.2024.149331

Liu, W.-Q.; Ji, X. Y.; Ba, F.; Zhang, Y. F.; Xu, H. L.; Huang, S. H.; Zheng, X.; Liu, Y. F.; Ling, S. J.; Jewett, M. C.; Li, J. Cell-Free Biosynthesis and Engineering of Ribosomally Synthesized Lanthipeptides. Nat. Commun. 2024, 15, 4336. https://doi.org/10.1038/s41467-024-48726-8

Nie, L.; Zhu, J. L.; Wu, X. Y.; Zhang, M. T.; Xiao, X.; Gao, R. H.; Wu, X. R.; Zhu, Y. F.; Chen, S. J.; Han, Z. Y.; Yu, Y.; Wang, S. G.; Ling, S. J.; Zhou, G. M. A Large-Scale Fabrication of Flexible, Ultrathin, and Robust Solid Electrolyte for Solid-State Lithium-Sulfur Batteries. Adv. Mater. 2024, 36 (25), 2400115. https://doi.org/10.1002/adma.202400115

Gao, W. L.; Jiang, Q. Q.; Guan, Y.; Huang, H. H.; Liu, S. Q.; Ling, S. J.; Zhou, L. Transfer Learning Improves Predictions in Lignin Content of Chinese Fir Based on Raman Spectra. Int. J. Biol. Macromol. 2024, 269, 132147. https://doi.org/10.1016/j.ijbiomac.2024.132147

孙奕; 吴伟; 文飘; 任婧; 郑可; 高文丽; 凌盛杰. 基于蒸腾驱动的柞蚕超纤纸电化学传感器的设计、制备及其溶剂在线鉴别应用研究. 高分子学报 2024, 55 (12), 1–12. https://doi.org/10.11777/j.issn1000-3304.2024.24171

2023

Wang, Y.; Gao, W. L.; Yang, S.; Chen, Q. L.; Ye, C.; Wang, H.; Zhang, Q.; Ren, J.; Ning, Z. J.; Chen, X.; Shao, Z. Z.; Li, J.; Liu, Y. F.; Ling, S. J. Humanoid Intelligent Display Platform for Audiovisual Interaction and Sound Identification. Nano-Micro Lett. 2023, 15, 221. https://doi.org/10.1007/s40820-023-01199-y

Dong, Z. R.; Zhang, Y. H.; Peng, R. X.; Shan, Y. C.; Ding, W.; Liu, Y. F.; Li, J.; Zhao, M. D.; Jiang, L. B.; Ling, S. J. Tendon Repair and Regeneration Using Bioinspired Fibrillation Engineering That Mimicked the Structure and Mechanics of Natural Tissue. ACS Nano 2023, 17 (18), 17858–17872. https://doi.org/10.1021/acsnano.3c03428

Peng, R. X.; Ba, F.; Li, J.; Cao, J. Y.; Zhang, R.; Liu, W.-Q.; Ren, J.; Liu, Y. F.; Li, J.; Ling, S. J. Embedding Living Cells with a Mechanically Reinforced and Functionally Programmable Hydrogel Fiber Platform. Adv. Mater. 2023, 35, 2305583. https://doi.org/10.1002/adma.202305583

Liu, Y. W.; Li, Y. S.; Wang, Q. Y.; Ren, J.; Ye, C.; Li, F. Y.; Ling, S. J.; Liu, Y. L.; Ling, D. S. Biomimetic Silk Architectures Outperform Animal Horns in Strength and Toughness. Adv. Sci. 2023, 10, 2303058. https://doi.org/10.1002/advs.202303058

Zhu, J. L.; Dai, C. C.; Yang, H. L.; Shan, Y. C.; Ren, J.; Liu, Y. F.; Li, J.; Chen, W. S.; Liang, J. R.; Ling, S. J. IntelliSense Bio-Ionotronics Battery for Early Warning of Geological Seepage. ACS Sens. 2023, 8 (7), 2731–2739. https://doi.org/10.1021/acssensors.3c00579

Zhu, J. L.; Yang, H. L.; Cao, L. T.; Dai, C. C.; Ren, J.; Liang, J. R.; Ling, S. J. Functionalization of Structural Materials through Electro-Blown Spinning of Ultrathin and Transparent Silk Fibroin Ionotronic Nanofiber Skin. Nano Today 2023, 50, 101873. https://doi.org/10.1016/j.nantod.2023.101873

Yang, S.; Zhao, C. X.; Yang, Y. H.; Ren, J.; Ling, S. J. The Fractal Network Structure of Silk Fibroin Molecules and Its Effect on Spinning of Silkworm Silk. ACS Nano 2023, 17 (8), 7662–7673. https://doi.org/10.1021/acsnano.3c00105

Cao, X. Y.; Ye, C.; Cao, L. T.; Shan, Y. C.; Ren, J.; Ling, S. J. Biomimetic Spun Silk Ionotronic Fibers for Intelligent Discrimination of Motions and Tactile Stimuli. Adv. Mater. 2023, 35, 2300447. https://doi.org/10.1002/adma.202300447

Cao, L. T.; Ye, C.; Zhang, H.; Yang, S.; Shan, Y. C.; Lv, Z. C.; Ren, J.; Ling, S. J. An Artificial Motion and Tactile Receptor Constructed by Hyperelastic Double Physically Crosslinked Silk Fibroin Ionoelastomer. Adv. Funct. Mater. 2023, 33, 2301404. https://doi.org/10.1002/adfm.202301404

Hu, Y. L.; Ma, Y.; Liu, L.; Yu, J.; Cui, J.; Ling, S. J.; Fan, Y. M. Nanosilk Template-Guided/Induced Construction of Brush-/Flower-like 3D Nanostructures. ACS Appl. Mater. Interfaces 2023, 15 (11), 14654–14663. https://doi.org/10.1021/acsami.2c20339

Zhang, H.; Cao, L. T.; Li, J.; Liu, Y. F.; Lv, Z. C.; Ren, J.; Shao, Z. Z.; Ling, S. J. Dual Physically Crosslinked Silk Fibroin Ionoelastomer with Ultrahigh Stretchability and Low Hysteresis. Chem. Mater. 2023, 35 (4), 1752–1761. https://doi.org/10.1021/acs.chemmater.2c03536

Dai, C. C.; Ye, C.; Ren, J.; Yang, S.; Cao, L. T.; Yu, H. P.; Liu, S. X.; Shao, Z. Z.; Li, J.; Chen, W. S.; Ling, S. J. Humanoid Ionotronic Skin for Smart Object Recognition and Sorting. ACS Mater. Lett. 2023, 5 (1), 189–201. https://doi.org/10.1021/acsmaterialslett.2c00783

Dai, C. C.; Wang, Y.; Shan, Y. C.; Ye, C.; Lv, Z. C.; Yang, S.; Cao, L. T.; Ren, J.; Yu, H. P.; Liu, S. X.; Shao, Z. Z.; Li, J.; Chen, W. S.; Ling, S. J. Cytoskeleton-Inspired Hydrogel Ionotronics for Tactile Perception and Electroluminescent Display in Complex Mechanical Environments. Mater. Horiz. 2023, 10, 136–148. https://doi.org/10.1039/D2MH01034H

Wen, P.; Ren, J.; Ling, S. J. Transpiration-Driven Electrokinetic Power Generator for Early Warning and Forecast of Geological Seepage. ACS Appl. Electron. Mater. 2023, 5 (4), 2082–2092. https://doi.org/10.1021/acsaelm.2c01747

Wen, P.; Ren, J.; Zhang, Q.; Ling, S. J. Flame-Retardant and Fire-Sensing Packaging Papers Enabled by Diffusion-Driven Self-Assembly of Graphene Oxide and Branched Polyethyleneimine Coatings. Coatings 2023, 13 (6), 1047. https://doi.org/10.3390/coatings13061047

Zhao, X. W.; Wu, C. H.; Dai, D. J.; Ren, J.; Li, T.; Ling, S. J. Silk Nanofibrils-MOF Composite Membranes for Pollutant Removal from Water. iScience 2023, 26 (8), 107290. https://doi.org/10.1016/j.isci.2023.107290

Zhang, R.; Liu, W.-Q.; Ling, S. J.; Li, J. Combining Cell-Free Expression and Multifactor Optimization for Enhanced Biosynthesis of Cinnamyl Alcohol. J. Agric. Food Chem. 2023, 71 (22), 8551–8557. https://doi.org/10.1021/acs.jafc.3c02340

Ba, F.; Ji, X. Y.; Huang, S. H.; Zhang, Y. F.; Liu, W.-Q.; Liu, Y. F.; Ling, S. J.; Li, J. Engineering Escherichia coli to Utilize Erythritol as Sole Carbon Source. Adv. Sci. 2023, 10, 2207008. https://doi.org/10.1002/advs.202207008

Chen, Y. L.; Liu, W.-Q.; Zheng, X.; Liu, Y. F.; Ling, S. J.; Li, J. Cell-Free Biosynthesis of Lysine-Derived Unnatural Amino Acids with Chloro, Alkene, and Alkyne Groups. ACS Synth. Biol. 2023, 12 (4), 1349–1357. https://doi.org/10.1021/acssynbio.3c00132

Zhou, B.; Miao, B. L.; Gao, Y.; Yu, A. S.; Shao, Z. Z. Self-Assembled Protein Nanofilm Regulating Uniform Zn Nucleation and Deposition Enabling Long-Life Zn Anodes. Small 2023, 19 (35), 2300895. https://doi.org/10.1002/smll.202300895

Chen, N.; Jin, W. H.; Gao, H.; Hong, J. C.; Sun, L. Y.; Yao, J. R.; Chen, X.; Chen, J.; Chen, S. Y.; Shao, Z. Z. Sequential Intervention of Anti-Inflammatory and Osteogenesis with Silk Fibroin Coated Polyethylene Terephthalate Artificial Ligaments for Anterior Cruciate Ligament Reconstruction. J. Mater. Chem. B 2023, 11, 8281–8290. https://doi.org/10.1039/D3TB00911D

Chen, N.; Luo, F. Y.; Yang, G. W.; Yao, J. R.; Chen, X.; Shao, Z. Z. Production of Functional Materials Derived from Regenerated Silk Fibroin by Utilizing 3D Printing and Biomimetic Enzyme-Induced Mineralization. Chin. J. Polym. Sci. 2024, 42, 299–310. https://doi.org/10.1007/s10118-023-3059-3

Da, G. H.; Ma, Y. Q.; Lin, Q. R.; Shao, Z. Z. Regenerated Silk Fibroin Hydrogel with Laponite/Polydopamine Composite Nanoparticles. Acta Polym. Sin. 2023, 54 (1), 95–105. https://doi.org/10.11777/j.issn1000-3304.2022.22208

Hong, J. C.; Lin, Q. R.; Shao, Z. Z. Bridging Biocondensation and Biomimetic Fibrillation by Regulating Intra- and Interchain Hydrogen Bonds in Artificial Biomacromolecular Condensates. ACS Macro Lett. 2023, 12 (7), 888–893. https://doi.org/10.1021/acsmacrolett.3c00172

Yin, X. Y.; Gu, K.; Shao, Z. Z. Preparation of the Protein/Polyphenylboronic Acid Nanospheres for Drug Loading and Unloading. Acta Chim. Sin. 2023, 81 (2), 116–123. https://doi.org/10.6023/A22100434

Miao, B. L.; Liu, Y.; Zhang, A. L.; Cao, Y.; Zhong, R.; Liu, J. X.; Shao, Z. Z. An in Situ Grown Ultrathin and Robust Protein Nanocoating for Mitigating Thromboembolic Issues Associated with Cardiovascular Medical Devices. Biomater. Sci. 2023, 11 (23), 7655–7662. https://doi.org/10.1039/D3BM01188G

Sun, L. Y.; Lu, M. Q.; Chen, L.; Zhao, B. J.; Yao, J. R.; Shao, Z. Z.; Chen, X.; Liu, Y. H. Silk-Inorganic Nanoparticle Hybrid Hydrogel as an Injectable Bone Repairing Biomaterial. J. Funct. Biomater. 2023, 14 (2), 86. https://doi.org/10.3390/jfb14020086

Chen, Q. L.; Wu, M.; Yao, J. R.; Shao, Z. Z.; Chen, X. Enzyme/Inorganic Nanoparticle Dual-Loaded Animal Protein/Plant Protein Composite Nanospheres and Their Synergistic Effect in Cancer Therapy. J. Mater. Chem. B 2023, 11 (20), 4529–4538. https://doi.org/10.1039/D3TB00070B

Chen, L.; Sun, L. Y.; Liu, W.; Yao, J. R.; Shao, Z. Z.; Zhao, B. J.; Chen, X. Long-Lasting Thixotropic Natural Polymeric Hydrogel Based on Silk Nanofibrils. ACS Biomater. Sci. Eng. 2023, 9 (7), 4168–4177. https://doi.org/10.1021/acsbiomaterials.3c00574

Ji, Z. Y.; Yao, J. R.; Shao, Z. Z.; Chen, X. Zein/Chitosan Composite Nanospheres for Controlled Release of Fragrances. Mater. Lett. 2023, 349, 134863. https://doi.org/10.1016/j.matlet.2023.134863

Luo, Y. Y.; Xiao, M. L.; Almaqrami, B. S.; Kang, H.; Shao, Z. Z.; Chen, X.; Zhang, Y. Regenerated Silk Fibroin Based on Small Aperture Scaffolds and Marginal Sealing Hydrogel for Osteochondral Defect Repair. Biomater. Res. 2023, 27 (1), 50. https://doi.org/10.1186/s40824-023-00370-1

Xu, Y. L.; Chen, Q. L.; Shao, Z. Z.; Wei, J. H.; Zhu, X. Y.; Rong, A.; Chen, X.; Ni, Y. S.; Jiang, Y. Evaluation of New Robust Silk Fibroin Hydrogels for Posterior Scleral Reinforcement in Rabbits. Front. Bioeng. Biotechnol. 2023, 11, 1211688. https://doi.org/10.3389/fbioe.2023.1211688

2022

Lv, Z. C.; Cao, L. T.; Ren, J.; Ling, S. J. Understanding the Mechanical 'Shakedown' of Hydrogel Ionotronics for Realizing Their Highly Functional Stability. Polymer 2022, 262, 125498. https://doi.org/10.1016/j.polymer.2022.125498

Liu, Q.; Li, X.; Zhang, H.; Ren, J.; Yang, S.; Cao, L. T.; Liang, J. R.; Ling, S. J. IntelliSense Silk Fibroin Ionotronic Batteries for Wildfire Detection and Alarm. Nano Energy 2022, 101, 107630. https://doi.org/10.1016/j.nanoen.2022.107630

Zhang, S.; Zhang, Y.; Huang, Y. P.; Lin, B. Q.; Ling, S. J.; Mei, C. T.; Pan, M. Z. Intelligent Coating Based on Metal-Insulator Transitional Ti₃O₅ towards Fire Sensing and Protection. Chem. Eng. J. 2022, 450, 137910. https://doi.org/10.1016/j.cej.2022.137910

Chen, Z. H.; Zhang, T. W.; Chen, C.-T.; Yang, S.; Lv, Z. C.; Cao, L. T.; Ren, J.; Shao, Z. Z.; Jiang, L. B.; Ling, S. J. Mechanically and Electrically Biocompatible Hydrogel Ionotronic Fibers for Fabricating Structurally Stable Implants and Enabling Noncontact Physioelectrical Modulation. Mater. Horiz. 2022, 9 (6), 1735–1749. https://doi.org/10.1039/D2MH00296E

Zhang, Y. H.; Ye, S. S.; Cao, L. T.; Lv, Z. C.; Ren, J.; Shao, Z. Z.; Yao, Y.; Ling, S. J. Natural Silk Spinning-Inspired Meso-Assembly-Processing Engineering Strategy for Fabricating Soft Tissue-Mimicking Biomaterials. Adv. Funct. Mater. 2022, 32, 2200267. https://doi.org/10.1002/adfm.202200267

Zhao, C. X.; Liu, Y. W.; Lv, Z. C.; Cao, L. T.; Ren, J.; Shao, Z. Z.; Ling, S. J. Silk Fibroin Nacre. Adv. Fiber Mater. 2022, 4, 1191–1208. https://doi.org/10.1007/s42765-022-00185-y

Ye, C.; Yang, S.; Ren, J.; Dong, S. J.; Cao, L. T.; Pei, Y.; Ling, S. J. Electroassisted Core-Spun Triboelectric Nanogenerator Fabrics for IntelliSense and Artificial Intelligence Perception. ACS Nano 2022, 16 (3), 4415–4425. https://doi.org/10.1021/acsnano.1c10680

Zhang, W. W.; Yang, S.; Peng, R. X.; Shu, T.; Ren, J.; Zhong, J. J.; Qi, Z. M.; Chen, M.; Tang, Y. Z.; Fan, Y. M.; Shao, Z. Z.; Ling, S. J. Hierarchically Non-Uniform Structures Determine the Hydro-Actuated Bending Deformation of Camel Hair. Cell Rep. Phys. Sci. 2022, 3 (3), 100793. https://doi.org/10.1016/j.xcrp.2022.100793

Yang, S.; Zhao, C. X.; Ren, J.; Zheng, K.; Shao, Z. Z.; Ling, S. J. Acquiring Structural and Mechanical Information of a Fibrous Network through Deep Learning. Nanoscale 2022, 14, 5044–5053. https://doi.org/10.1039/D2NR00372D

Dai, M.; Zhao, F.; Fan, J. J.; Li, Q.; Yang, Y.; Fan, Z. J.; Ling, S. J.; Yu, H. P.; Liu, S. X.; Li, J.; Chen, W. S.; Yu, G. H. A Nanostructured Moisture-Absorbing Gel for Fast and Large-Scale Passive Dehumidification. Adv. Mater. 2022, 34, 2200865. https://doi.org/10.1002/adma.202200865

Wang, Y.; Ren, J.; Lv, Z. C.; Cao, L. T.; Lin, S. H.; Pei, Y.; Zhang, Q.; Shao, Z. Z.; Ling, S. J. Direct Functionalization of Natural Silks through Continuous Force-Reeling Technique. Chem. Eng. J. 2022, 435 (1), 134901. https://doi.org/10.1016/j.cej.2022.134901

Gao, W. L.; Shu, T.; Guan, Y.; Ling, S. J.; Liu, S. Q.; Zhou, L. Novel Strategy for Establishment of an FT-Raman Spectroscopy Based Quantitative Model for Poplar Holocellulose Content Determination. Carbohydr. Polym. 2022, 277, 118793. https://doi.org/10.1016/j.carbpol.2021.118793

Lin, S. H.; Cao, L. T.; Lv, Z. C.; Ren, J.; Ling, S. J. Quantitative Evaluation of Pseudo Strain Signals Caused by Yarn Structural Deformation. Adv. Fiber Mater. 2022, 4 (2), 214–225. https://doi.org/10.1007/s42765-021-00113-4

Lin, Q. R.; Yang, Y. H.; Shao, Z. Z. Non-metallic T₂-MRI Agents Based on Conjugated Polymers. Nat. Commun. 2022, 13 (1), 1994. https://doi.org/10.1038/s41467-022-29569-x

Xie, J. Y.; Gu, K.; Zhao, Y.; Yao, J. R.; Chen, X.; Shao, Z. Z. Enhancement of the Mechanical Properties of Poly(lactic acid)/Epoxidized Soybean Oil Blends by the Addition of 3-Aminophenylboronic Acid. ACS Omega 2022, 7 (21), 17841–17848. https://doi.org/10.1021/acsomega.2c01355

Wen, H. J.; Chen, X. Y.; Wang, Y.; Yao, J. R.; Chen, X.; Ling, S. J.; Shao, Z. Z. Proteinic Artificial Skin with Molecularly Encoded Coloration. ACS Appl. Mater. Interfaces 2022, 14 (34), 39322–39331. https://doi.org/10.1021/acsami.2c07666

Chen, N.; Zhang, X. B.; Lyu, J. Y.; Zhao, G. L.; Gu, K.; Xia, J.; Chen, Z. C.; Shao, Z. Z. Preparation of a Novel Regenerated Silk Fibroin-Based Hydrogel for Extrusion Bioprinting. Soft Matter 2022, 18 (38), 7360–7368. https://doi.org/10.1039/D2SM00984F

Lu, M. Q.; Wu, M.; Huang, Y. F.; Yao, J. R.; Shao, Z. Z.; Chen, X. Animal Protein-Plant Protein Composite Nanospheres for Dual-Drug Loading and Synergistic Cancer Therapy. J. Mater. Chem. B 2022, 10 (20), 3798–3807. https://doi.org/10.1039/D2TB00368F

Chen, L.; Sun, L. Y.; Yao, J. R.; Zhao, B. J.; Shao, Z. Z.; Chen, X. Robust Silk Protein Hydrogels Made by a Facile One-Step Method and Their Multiple Applications. ACS Appl. Bio Mater. 2022, 5 (6), 3086–3094. https://doi.org/10.1021/acsabm.2c00328

Lu, M. Q.; Sun, L. Y.; Yao, J. R.; Zhao, B. J.; Liu, Y. H.; Shao, Z. Z.; Chen, X. Protein-Inorganic Hybrid Porous Scaffolds for Bone Tissue Engineering. J. Mater. Chem. B 2022, 10 (34), 6546–6556. https://doi.org/10.1039/D2TB00989G

Chen, Q. Y.; Liu, Y.; Gu, K.; Yao, J. R.; Shao, Z. Z.; Chen, X. Silk-Based Electrochemical Sensor for the Detection of Glucose in Sweat. Biomacromolecules 2022, 23 (9), 3928–3935. https://doi.org/10.1021/acs.biomac.2c00753

Wen, H. J.; Yao, J. R.; Chen, X.; Ling, S. J.; Shao, Z. Z. Silk-Derived Peptide Nanospirals Assembled by Self-Propelled Worm-like Filaments. Nano Res. 2023, 16 (1), 1414–1420. https://doi.org/10.1007/s12274-022-4671-1

2021

Ling, S. J. Fibrous Proteins: Design, Synthesis, and Assembly; Humana: New York, NY, 2021. https://doi.org/10.1007/978-1-0716-1574-4

Yang, G. W.; Gu, K.; Shao, Z. Z. The Investigation from Animal Silks to Silk Protein-Based Materials. Acta Polym. Sin. 2021, 52 (1), 16–28. https://doi.org/10.11777/j.issn1000-3304.2020.20142

Duan, Y.; Chen, X.; Shao, Z. Z. Comparison of Native and Regenerated Antheraea Pernyi Silk Fibroin. Mater. Sci. (Medžiagotyra) 2021, 27 (1), 57–62. https://doi.org/10.5755/j02.ms.22784

Tao, Y.; Gu, K.; Shao, Z. Z. Pressure Sensing Material Based on Reduced Graphene Oxide/Silk Fibroin Sponge. Acta Polym. Sin. 2021, 52 (2), 158–165. https://doi.org/10.11777/j.issn1000-3304.2020.20189

Wu, K.; Zhao, Y.; Li, J. Q.; Yao, J. R.; Chen, X.; Shao, Z. Z. Crystallization, Mechanical, and Antimicrobial Properties of Diallyl Cyanuric Derivative-Grafted Polypropylene. ACS Omega 2021, 6 (19), 12794–12800. https://doi.org/10.1021/acsomega.1c01100

Yan, Z.; Chen, W. B.; Jin, W. H.; Sun, Y. Y.; Cai, J. Y.; Gu, K.; Mi, R. X.; Chen, N.; Chen, S. Y.; Shao, Z. Z. An Interference Screw Made Using a Silk Fibroin-Based Bulk Material with High Content of Hydroxyapatite for Anterior Cruciate Ligament Reconstruction in a Rabbit Model. J. Mater. Chem. B 2021, 9 (26), 5352–5364. https://doi.org/10.1039/D1TB01006A

Wang, S. H.; Sun, L. N.; Cao, H.; Zhong, Y. M.; Shao, Z. Z. Development of a Dual-Drug-Loaded Silk Fibroin Hydrogel and Study on Its Drugs Release Behaviors. Acta Chim. Sin. 2021, 79 (8), 1023–1029. https://doi.org/10.6023/A21050203

Wu, M.; Liu, W.; Yao, J. R.; Shao, Z. Z.; Chen, X. Silk Microfibrous Mats with Long-Lasting Antimicrobial Function. J. Mater. Sci. Technol. 2021, 63, 203–209. https://doi.org/10.1016/j.jmst.2020.02.060

Wu, M.; Han, Z. Y.; Liu, W.; Yao, J. R.; Zhao, B. J.; Shao, Z. Z.; Chen, X. Silk-Based Hybrid Microfibrous Mats as Guided Bone Regeneration Membranes. J. Mater. Chem. B 2021, 9 (8), 2025–2032. https://doi.org/10.1039/D0TB02687E

Chen, Q. Y.; Tang, H.; Liu, J. L.; Wang, R. R.; Sun, J.; Yao, J. R.; Shao, Z. Z.; Chen, X. Silk-Based Pressure/Temperature Sensing Bimodal Ionotronic Skin with Stimulus Discriminability and Low Temperature Workability. Chem. Eng. J. 2021, 422, 130091. https://doi.org/10.1016/j.cej.2021.130091

Zhao, B. H.; Chen, Q. Y.; Da, G. H.; Yao, J. R.; Shao, Z. Z.; Chen, X. A Highly Stretchable and Anti-Freezing Silk-Based Conductive Hydrogel for Application as a Self-Adhesive and Transparent Ionotronic Skin. J. Mater. Chem. C 2021, 9 (28), 8955–8965. https://doi.org/10.1039/D1TC01587G

Liu, Y. Z.; Wang, W. Q.; Gu, K.; Yao, J. R.; Shao, Z. Z.; Chen, X. Poly(vinyl alcohol) Hydrogels with Integrated Toughness, Conductivity, and Freezing Tolerance Based on Ionic Liquid/Water Binary Solvent Systems. ACS Appl. Mater. Interfaces 2021, 13 (24), 29008–29020. https://doi.org/10.1021/acsami.1c06006

Lv, Z. C.; Ren, J.; Lin, S. H.; Pei, Y.; Shao, Z. Z.; Ling, S. J. Understanding the Continuous Dynamic Mechanical Behavior of Animal Silk. Macromolecules 2021, 54 (1), 249–258. https://doi.org/10.1021/acs.macromol.0c02305

Dong, S. J.; Wang, Y.; Pei, Y.; Zhang, Q.; Li, B.; Ling, S. J.; Ren, J. Water Collecting Carbon Nanotube Yarn with Biomimetic Composition and Structure. Compos. Commun. 2021, 28, 100960. https://doi.org/10.1016/j.coco.2021.100960

Shu, T.; Cui, J.; Lv, Z. C.; Cao, L. T.; Ren, J.; Ling, S. J. Moderate Conformational Transition Promotes the Formation of a Self-Reinforced Highly Oriented Silk Fibroin Network Structure. Soft Matter 2021, 17, 9576–9585. https://doi.org/10.1039/D1SM01120K

Yang, S.; Ling, S. J. An Artificial Intelligence-Based Motion Trajectory Prediction of Fibrous Matters. Adv. Intell. Syst. 2021, 4 (1), 2100136. https://doi.org/10.1002/aisy.202100136

Dong, S. J.; Zhang, Y. H.; Li, B.; Ren, J.; Ling, S. J.; Cao, L. T. Self-Adhesive and Contractile Silk Fibroin/Graphene Nano-Ionotronic Skin for Strain Sensing of Irregular Surfaces. Nanotechnology 2021, 32, 475505. https://doi.org/10.1088/1361-6528/ac1cee

Cao, L. T.; Liu, Q.; Ren, J.; Chen, W. S.; Pei, Y.; Kaplan, D. L.; Ling, S. J. Electro-Blown Spun Silk/Graphene Nanoionotronic Skin for Multifunctional Fire Protection and Alarm. Adv. Mater. 2021, 33, 2102500. https://doi.org/10.1002/adma.202102500

Shu, T.; Lv, Z. C.; Chen, C.-T.; Gu, G. X.; Ren, J.; Cao, L. T.; Pei, Y.; Ling, S. J.; Kaplan, D. L. Mechanical Training-Driven Structural Remodeling: A Rational Route for Outstanding Highly Hydrated Silk Materials. Small 2021, 17, 2102660. https://doi.org/10.1002/smll.202102660

Dong, S. J.; Gan, Z.; Chen, X.; Pei, Y.; Li, B.; Ren, J.; Wang, Y.; He, H. Y.; Ling, S. J. A Bioinspired Interfacial Design to Toughen Carbon Nanotube Fibers. Mater. Chem. Front. 2021, 5, 5706–5717. https://doi.org/10.1039/D1QM00592H

Lv, Z. C.; Shu, T.; Ren, J.; Cao, L. T.; Pei, Y.; Shao, Z. Z.; Ling, S. J. Mechanism of Mechanical Training-Induced Self-Reinforced Viscoelastic Behavior of Highly Hydrated Silk Materials. Biomacromolecules 2021, 22 (5), 2189–2196. https://doi.org/10.1021/acs.biomac.1c00205

Qi, P.; Ren, J.; Ling, S. J. Animal Silk-Derived Amorphous Carbon Fibers for Electricity Generation and Solar Steam Evaporation. Front. Chem. 2021, 9, 669797. https://doi.org/10.3389/fchem.2021.669797

Yang, S.; Liu, Q.; Ren, J.; Ling, S. J. Influence of Hydrated Protons on Temperature and Humidity Responsiveness of Silk Fibroin Hydrogel Ionotronics. Giant 2021, 5, 100044. https://doi.org/10.1016/j.giant.2020.100044

Xiao, Y.; Liu, Y.; Zhang, W. W.; Qi, P.; Ren, J.; Pei, Y.; Ling, S. J. Formation, Structure, and Mechanical Performance of Silk Nanofibrils Produced by Heat-Induced Self-Assembly. Macromol. Rapid Commun. 2021, 42 (3), e2000435. https://doi.org/10.1002/marc.202000435

Wang, Y.; Ren, J.; Ye, C.; Pei, Y.; Ling, S. J. Thermochromic Silks for Temperature Management and Dynamic Textile Displays. Nano-Micro Lett. 2021, 13, 72. https://doi.org/10.1007/s40820-021-00591-6

Wang, M.; Sun, T.; Wan, D.; Dai, M.; Ling, S. J.; Wang, J.; Liu, Y.; Fang, Y.; Xu, S.; Yeo, J.; Yu, H. P.; Liu, S. X.; Wang, Q.; Li, J.; Yang, Y.; Fan, Z. J.; Chen, W. S. Solar-Powered Nanostructured Biopolymer Hygroscopic Aerogels for Atmospheric Water Harvesting. Nano Energy 2021, 80, 105569. https://doi.org/10.1016/j.nanoen.2020.105569

Shu, T.; Zheng, K.; Zhang, Z.; Ren, J.; Wang, Z.; Pei, Y.; Yeo, J.; Gu, G. X.; Ling, S. J. Birefringent Silk Fibroin Hydrogel Constructed via Binary Solvent-Exchange-Induced Self-Assembly. Biomacromolecules 2021, 22 (5), 1955–1965. https://doi.org/10.1021/acs.biomac.1c00065

Liu, Y.; Ren, J.; Pei, Y.; Qi, Z. M.; Chen, M.; Ling, S. J. Structural Information of Biopolymer Nanofibrils by Infrared Nanospectroscopy. Polymer 2021, 219, 123534. https://doi.org/10.1016/j.polymer.2021.123534

Jiang, M.; Shu, T.; Ye, C.; Ren, J.; Ling, S. J. Predicting the Conformations of the Silk Protein through Deep Learning. Analyst 2021, 146 (8), 2490–2498. https://doi.org/10.1039/D1AN00290B

Ren, J.; Liu, Q.; Pei, Y.; Wang, Y.; Yang, S.; Lin, S. H.; Chen, W. S.; Ling, S. J.; Kaplan, D. L. Bioinspired Energy Storage and Harvesting Devices. Adv. Mater. Technol. 2021, 6 (6), 2001301. https://doi.org/10.1002/admt.202001301

Fang, Y.; Jing, C.; Li, G.; Ling, S. J.; Wang, Z.; Lu, P.; Li, Q.; Dai, C. C.; Gao, S.; Chen, B.; Bai, L. L.; Zhang, H.; Liu, T.; Wang, Q.; Li, J.; Yu, H. P.; Liu, S. X.; Chen, W. S. Wood-Derived Systems for Sustainable Oil/Water Separation. Adv. Sustain. Syst. 2021, 5 (8), 2100039. https://doi.org/10.1002/adsu.202100039

Bai, L.; Li, Q.; Yang, Y.; Ling, S. J.; Yu, H. P.; Liu, S. X.; Li, J.; Chen, W. S. Biopolymer Nanofibers for Nanogenerator Development. Research 2021, 2021, 1843061. https://doi.org/10.34133/2021/1843061

2020

Dai, J.; Lu, Y.; He, X. Y.; Zhong, C.; Lin, B. L.; Ling, S. J.; Gong, J. K.; Yao, Y. Vertical Nanopillar Induces Deformation of Cancer Cell and Alteration of ATF3 Expression. Appl. Mater. Today 2020, 20, 100753. https://doi.org/10.1016/j.apmt.2020.100753

Ye, C.; Dong, S. J.; Ren, J.; Ling, S. J. Ultrastable and High-Performance Silk Energy Harvesting Textiles. Nano-Micro Lett. 2020, 12 (1), 12. https://doi.org/10.1007/s40820-019-0348-z

Wang, W. Q.; Liu, Y. Z.; Wang, S. Q.; Fu, X. M.; Zhao, T. C.; Chen, X.; Shao, Z. Z. Physically Cross-Linked Silk Fibroin-Based Tough Hydrogel Electrolyte with Exceptional Water Retention and Freezing Tolerance. ACS Appl. Mater. Interfaces 2020, 12 (22), 25353–25362. https://doi.org/10.1021/acsami.0c04890

Hu, L. L.; Chen, Q. Y.; Yao, J. R.; Shao, Z. Z.; Chen, X. Structural Changes in Spider Dragline Silk after Repeated Supercontraction-Stretching Processes. Biomacromolecules 2020, 21 (12), 5306–5314. https://doi.org/10.1021/acs.biomac.0c01428

Wang, J.; Mi, R. X.; Zhao, G. L.; Shi, J.; Chen, J.; Liu, C.; Shao, Z. Z.; Xia, J. A Silk-Based High Impact Composite for the Core Decompression of the Femoral Head. J. Mater. Chem. B 2020, 8 (42), 9734–9743. https://doi.org/10.1039/D0TB01602K

Wu, K.; Li, J. Q.; Chen, X.; Yao, J. R.; Shao, Z. Z. Synthesis of Novel Multi-Hydroxyl N-Halamine Precursors Based on Barbituric Acid and Their Applications in Antibacterial Poly(ethylene terephthalate) (PET) Materials. J. Mater. Chem. B 2020, 8 (37), 8695–8701. https://doi.org/10.1039/D0TB01474E

Zhao, Y.; Zhao, B. H.; Wei, B. L.; Wei, Y. X.; Yao, J. R.; Zhang, H. L.; Chen, X.; Shao, Z. Z. Enhanced Compatibility between Poly(lactic acid) and Poly(butylene adipate-co-terephthalate) by Incorporation of N-Halamine Epoxy Precursor. Int. J. Biol. Macromol. 2020, 165, 460–471. https://doi.org/10.1016/j.ijbiomac.2020.09.168

Gong, D. F.; Lin, Q. R.; Shao, Z. Z.; Chen, X.; Yang, Y. H. Preparing 3D-Printable Silk Fibroin Hydrogels with Robustness by a Two-Step Crosslinking Method. RSC Adv. 2020, 10 (45), 27225–27234. https://doi.org/10.1039/D0RA04789A

Liu, J. L.; Chen, Q. Y.; Liu, Q.; Zhao, B. H.; Ling, S. J.; Yao, J. R.; Shao, Z. Z.; Chen, X. Intelligent Silk Fibroin Ionotronic Skin for Temperature Sensing. Adv. Mater. Technol. 2020, 5 (7), 2000430. https://doi.org/10.1002/admt.202000430

Wei, Y.; Yao, J. R.; Shao, Z. Z.; Chen, X. Water-Resistant Zein-Based Adhesives. ACS Sustainable Chem. Eng. 2020, 8 (20), 7668–7679. https://doi.org/10.1021/acssuschemeng.0c01446

Wang, H.; Dong, Q.; Yao, J. R.; Shao, Z. Z.; Ma, J.; Chen, X. Colorless Silk/Copper Sulfide Hybrid Fiber and Fabric with Spontaneous Heating Property under Sunlight. Biomacromolecules 2020, 21 (4), 1596–1603. https://doi.org/10.1021/acs.biomac.0c00100

Hu, L. L.; Han, Y.; Ling, S. J.; Huang, Y. F.; Yao, J. R.; Shao, Z. Z.; Chen, X. Direct Observation of Native Silk Fibroin Conformation in Silk Gland of Bombyx mori Silkworm. ACS Biomater. Sci. Eng. 2020, 6 (4), 1874–1879. https://doi.org/10.1021/acsbiomaterials.9b01827

Dong, Q.; Cai, J. Y.; Wang, H.; Chen, S. Y.; Liu, Y.; Yao, J. R.; Shao, Z. Z.; Chen, X. Artificial Ligament Made from Silk Protein/Laponite Hybrid Fibers. Acta Biomater. 2020, 106, 102–113. https://doi.org/10.1016/j.actbio.2020.01.043

Zhao, Y.; Wei, B. L.; Wu, M.; Zhang, H. L.; Yao, J. R.; Chen, X.; Shao, Z. Z. Preparation and Characterization of Antibacterial Poly(lactic acid) Nanocomposites with N-Halamine Modified Silica. Int. J. Biol. Macromol. 2020, 155, 1468–1477. https://doi.org/10.1016/j.ijbiomac.2019.11.126

Dong, Q.; Fang, G. Q.; Huang, Y. F.; Hu, L. L.; Yao, J. R.; Shao, Z. Z.; Ling, S. J.; Chen, X. Effect of Stress on the Molecular Structure and Mechanical Properties of Supercontracted Spider Dragline Silks. J. Mater. Chem. B 2020, 8 (1), 168–176. https://doi.org/10.1039/C9TB02148E

Zhang, W. W.; Zheng, K.; Ren, J.; Fan, Y. M.; Ling, S. J. Strong, Ductile and Lightweight Bionanocomposites Constructed by Bioinspired Hierarchical Assembly. Compos. Commun. 2020, 17, 97–103. https://doi.org/10.1016/j.coco.2019.11.012

Zhang, W. W.; Ren, J.; Pei, Y.; Ye, C.; Fan, Y. M.; Qi, Z. M.; Ling, S. J. Analysis of the Contribution of Conformation and Fibrils on Tensile Toughness and Fracture Resistance of Camel Hairs. ACS Biomater. Sci. Eng. 2023, 9 (7), 3877–3884. https://doi.org/10.1021/acsbiomaterials.0c00892

Ye, C.; Xu, Q.; Ren, J.; Ling, S. J. Violin String Inspired Core-Sheath Silk/Steel Yarns for Wearable Triboelectric Nanogenerator Applications. Adv. Fiber Mater. 2020, 2 (1), 24–33. https://doi.org/10.1007/s42765-019-00023-w

Xu, Q.; Ying, P.; Ren, J.; Kong, N.; Wang, Y.; Li, Y. G.; Yao, Y.; Kaplan, D. L.; Ling, S. J. Biomimetic Design for Bio-Matrix Interfaces and Regenerative Organs. Tissue Eng., Part B 2021, 27 (5), 411–429. https://doi.org/10.1089/ten.TEB.2020.0234

Wu, D.; Ye, C.; Liu, Y.; Ren, J.; Yao, Y.; Ling, S. J. Light, Strong, and Ductile Architectures Achieved by Silk Fiber Welding Processing. ACS Omega 2020, 5 (21), 11955–11961. https://doi.org/10.1021/acsomega.0c00579

Wang, Z.; Lin, S. H.; Ren, J.; Pei, Y.; Chen, M.; Qi, Z. M.; Shao, Z. Z.; Ling, S. J. Understanding Humidity-Induced Actuation in Antheraea pernyi Silks. Giant 2020, 3, 100029. https://doi.org/10.1016/j.giant.2020.100029

Wang, Y.; Huang, W.; Wang, Y.; Mu, X.; Ling, S. J.; Yu, H. P.; Chen, W. S.; Guo, C.; Watson, M. C.; Yu, Y.; Black, L. D., 3rd; Li, M.; Omenetto, F. G.; Li, C.; Kaplan, D. L. Stimuli-Responsive Composite Biopolymer Actuators with Selective Spatial Deformation Behavior. Proc. Natl. Acad. Sci. U.S.A. 2020, 117 (25), 14602–14608. https://doi.org/10.1073/pnas.2002996117

Wang, Q.; Ling, S. J.; Yao, Q. Z.; Li, Q. Y.; Hu, D. B.; Dai, Q.; Weitz, D. A.; Kaplan, D. L.; Buehler, M. J.; Zhang, Y. Y. Observations of 3 nm Silk Nanofibrils Exfoliated from Natural Silkworm Silk Fibers. ACS Mater. Lett. 2020, 2 (2), 153–160. https://doi.org/10.1021/acsmaterialslett.9b00461

Peng, Z.; Wei, Q.; Chen, H.; Liu, Y.; Wang, F.; Jiang, X.; Liu, W.; Zhou, W.; Ling, S. J.; Ning, Z. J. Cs₀.₁₅FA₀.₈₅PbI₃/CsₓFA₁₋ₓPbI₃ Core/Shell Heterostructure for Highly Stable and Efficient Perovskite Solar Cells. Cell Rep. Phys. Sci. 2020, 1 (10), 100224. https://doi.org/10.1016/j.xcrp.2020.100224

Mu, X.; Wang, Y.; Guo, C.; Li, Y.; Ling, S. J.; Huang, W.; Cebe, P.; Hsu, H. H.; De Ferrari, F.; Jiang, X.; Xu, Q.; Balduini, A.; Omenetto, F. G.; Kaplan, D. L. 3D Printing of Silk Protein Structures by Aqueous Solvent-Directed Molecular Assembly. Macromol. Biosci. 2020, 20 (1), e1900191. https://doi.org/10.1002/mabi.201900191

Liu, Q.; Yang, S.; Ren, J.; Ling, S. J. Flame-Retardant and Sustainable Silk Ionotronic Skin for Fire Alarm Systems. ACS Mater. Lett. 2020, 2 (7), 712–720. https://doi.org/10.1021/acsmaterialslett.0c00083

Lin, S. H.; Wang, Z.; Chen, X.; Ren, J.; Ling, S. J. Ultrastrong and Highly Sensitive Fiber Microactuators Constructed by Force-Reeled Silks. Adv. Sci. 2020, 7 (6), 1902743. https://doi.org/10.1002/advs.201902743

Kong, N.; Wan, F. J.; Dai, W. Y.; Lu, Y.; Cheng, P. H.; Dai, J.; Li, Y. Y.; Gong, J. K.; Ling, S. J.; Yao, Y. Bioinspired Polypeptide as Building Blocks for Multifunctional Material Design. Appl. Mater. Today 2020, 20, 100683. https://doi.org/10.1016/j.apmt.2020.100683

Kong, N.; Wan, F. J.; Dai, W. Y.; Wu, P.; Su, C.; Peng, C.; Zheng, K.; Chen, X.; Ling, S. J.; Gong, J. K.; Yao, Y. A Cuboid Spider Silk: Structure-Function Relationship and Polypeptide Signature. Macromol. Rapid Commun. 2020, 41 (6), e1900583. https://doi.org/10.1002/marc.201900583

Guo, C.; Li, C.; Vu, H. V.; Hanna, P.; Lechtig, A.; Qiu, Y.; Mu, X.; Ling, S. J.; Nazarian, A.; Lin, S. J.; Kaplan, D. L. Thermoplastic Moulding of Regenerated Silk. Nat. Mater. 2020, 19 (1), 102–108. https://doi.org/10.1038/s41563-019-0560-8

Dai, J.; Wang, Y. Q.; Wu, D. H.; Wan, F. J.; Lu, Y.; Kong, N.; Li, X. C.; Gong, J. K.; Ling, S. J.; Yao, Y. Biointerface Mediates Cytoskeletal Rearrangement of Pancreatic Cancer Cell and Modulates Its Drug Sensitivity. Colloid Interface Sci. Commun. 2020, 35, 100250. https://doi.org/10.1016/j.colcom.2020.100250

2019

Wu, M.; Li, Z.; Yao, J. R.; Shao, Z. Z.; Chen, X. Pea Protein/Gold Nanocluster/Indocyanine Green Ternary Hybrid for Near-Infrared Fluorescence/Computed Tomography Dual-Modal Imaging and Synergistic Photodynamic/Photothermal Therapy. ACS Biomater. Sci. Eng. 2019, 5 (9), 4799–4807. https://doi.org/10.1021/acsbiomaterials.9b00414

Fu, C. J.; Wang, Y.; Guan, J.; Chen, X.; Vollrath, F.; Shao, Z. Z. Cryogenic Toughness of Natural Silk and a Proposed Structure-Function Relationship. Mater. Chem. Front. 2019, 3 (11), 2507–2513. https://doi.org/10.1039/C9QM00282K

Dong, T.; Mi, R. X.; Wu, M.; Zhong, N. P.; Zhao, X.; Chen, X.; Shao, Z. Z. The Regenerated Silk Fibroin Hydrogel with Designed Architecture Bioprinted by Its Microhydrogel. J. Mater. Chem. B 2019, 7 (27), 4328–4337. https://doi.org/10.1039/C9TB00783K

Cao, H.; Duan, Y.; Lin, Q. R.; Yang, Y. H.; Gong, Z.; Zhong, Y. M.; Chen, X.; Shao, Z. Z. Dual-Loaded, Long-Term Sustained Drug Releasing and Thixotropic Hydrogel for Localized Chemotherapy of Cancer. Biomater. Sci. 2019, 7 (7), 2975–2985. https://doi.org/10.1039/C9BM00395A

Wei, Y.; Hu, L. L.; Yao, J. R.; Shao, Z. Z.; Chen, X. Facile Dissolution of Zein Using a Common Solvent Dimethyl Sulfoxide. Langmuir 2019, 35 (20), 6640–6649. https://doi.org/10.1021/acs.langmuir.9b00689

Zhong, N. P.; Dong, T.; Chen, Z. C.; Guo, Y.; Shao, Z. Z.; Zhao, X. A Novel 3D-Printed Silk Fibroin-Based Scaffold Facilitates Tracheal Epithelium Proliferation in Vitro. J. Biomater. Appl. 2019, 34 (1), 3–11. https://doi.org/10.1177/0885328219845078

Wei, B. L.; Zhao, Y.; Wei, Y. X.; Yao, J. R.; Chen, X.; Shao, Z. Z. Morphology and Properties of a New Biodegradable Material Prepared from Zein and Poly(butylene adipate-terephthalate) by Reactive Blending. ACS Omega 2019, 4 (3), 5609–5616. https://doi.org/10.1021/acsomega.9b00210

Zhong, J. J.; Liu, Y.; Ren, J.; Tang, Y. Z.; Qi, Z. M.; Zhou, X.; Chen, X.; Shao, Z. Z.; Chen, M.; Kaplan, D. L.; Ling, S. J. Understanding Secondary Structures of Silk Materials via Micro- and Nano-Infrared Spectroscopies. ACS Biomater. Sci. Eng. 2019, 5 (7), 3161–3183. https://doi.org/10.1021/acsbiomaterials.9b00305

Zheng, K.; Ling, S. J. De Novo Design of Recombinant Spider Silk Proteins for Material Applications. Biotechnol. J. 2019, 14 (1), e1700753. https://doi.org/10.1002/biot.201700753

Zheng, K.; Hu, Y.; Zhang, W. W.; Yu, J.; Ling, S. J.; Fan, Y. M. Oxidizing and Nano-Dispersing the Natural Silk Fibers. Nanoscale Res. Lett. 2019, 14 (1), 250. https://doi.org/10.1186/s11671-019-3078-8

Ye, C.; Wang, J. J.; Xu, Y. Y.; Zheng, K.; Wang, X. Y.; Ling, S. J.; Kaplan, D. L. De Novo Synthesis and Assembly of Flexible and Biocompatible Physical Sensing Platforms. Adv. Mater. Technol. 2019, 4 (1), 1800141. https://doi.org/10.1002/admt.201800141

Ye, C.; Ren, J.; Wang, Y. L.; Zhang, W. W.; Qian, C.; Han, J.; Zhang, C. X.; Jin, K.; Buehler, M. J.; Kaplan, D. L.; Ling, S. J. Design and Fabrication of Silk Templated Electronic Yarns and Applications in Multifunctional Textiles. Matter 2019, 1 (5), 1411–1425. https://doi.org/10.1016/j.matt.2019.07.016

Yang, N.; Zhang, W. W.; Ye, C.; Chen, X.; Ling, S. J. Nanobiopolymers Fabrication and Their Life Cycle Assessments. Biotechnol. J. 2019, 14 (1), e1700754. https://doi.org/10.1002/biot.201700754

Yang, N.; Qi, P.; Ren, J.; Yu, H. P.; Liu, S. X.; Li, J.; Chen, W. S.; Kaplan, D. L.; Ling, S. J. Polyvinyl Alcohol/Silk Fibroin/Borax Hydrogel Ionotronics: A Highly Stretchable, Self-Healable, and Biocompatible Sensing Platform. ACS Appl. Mater. Interfaces 2019, 11 (26), 23632–23638. https://doi.org/10.1021/acsami.9b06920

Wang, Y. S.; Wang, J. L.; Ling, S. J.; Liang, H. W.; Dai, M.; Bai, L. L.; Li, Q.; Fan, Z. J.; Lee, S. Y.; Yu, H. P.; Liu, S. X.; Wang, Q. W.; Liu, Y. X.; Li, J.; Sun, T. M.; Chen, W. S. Wood-Derived Nanofibrillated Cellulose Hydrogel Filters for Fast and Efficient Separation of Nanoparticles. Adv. Sustain. Syst. 2019, 3 (9), 1900063. https://doi.org/10.1002/adsu.201900063

Wang, Q.; Ling, S. J.; Liang, X. P.; Wang, H. M.; Lu, H. J.; Zhang, Y. Y. Self-Healable Multifunctional Electronic Tattoos Based on Silk and Graphene. Adv. Funct. Mater. 2019, 29 (16), 1808695. https://doi.org/10.1002/adfm.201808695

Ren, J.; Wang, Y.; Yao, Y.; Wang, Y.; Fei, X.; Qi, P.; Lin, S. H.; Kaplan, D. L.; Buehler, M. J.; Ling, S. J. Biological Material Interfaces as Inspiration for Mechanical and Optical Material Designs. Chem. Rev. 2019, 119 (24), 12279–12336. https://doi.org/10.1021/acs.chemrev.9b00416

Ren, J.; Liu, Y. W.; Kaplan, D. L.; Ling, S. J. Interplay of Structure and Mechanics in Silk/Carbon Nanocomposites. MRS Bull. 2019, 44 (1), 53–58. https://doi.org/10.1557/mrs.2018.320

Liu, Y. W.; Ren, J.; Ling, S. J. Bioinspired and Biomimetic Silk Spinning. Compos. Commun. 2019, 13, 85–96. https://doi.org/10.1016/j.coco.2019.03.004

Lin, S. H.; Ye, C.; Zhang, W. W.; Xu, A.; Chen, S.; Ren, J.; Ling, S. J. Nanofibril Organization in Silk Fiber as Inspiration for Ductile and Damage-Tolerant Fiber Design. Adv. Fiber Mater. 2019, 1 (3–4), 231–240. https://doi.org/10.1007/s42765-019-00022-x

2018

Lin, Q. R.; Yang, Y. H.; Ma, Y. Q.; Zhang, R.; Wang, J.; Chen, X.; Shao, Z. Z. Bandgap Engineered Polypyrrole-Polydopamine Hybrid with Intrinsic Raman and Photoacoustic Imaging Contrasts. Nano Lett. 2018, 18 (12), 7485–7493. https://doi.org/10.1021/acs.nanolett.8b02901

Liu, J.; He, T.; Fang, G. Q.; Wang, R.; Kamoun, E. A.; Yao, J. R.; Shao, Z. Z.; Chen, X. Environmentally Responsive Composite Films Fabricated Using Silk Nanofibrils and Silver Nanowires. J. Mater. Chem. C 2018, 6 (47), 12940–12947. https://doi.org/10.1039/C8TC04549F

Yao, M.; Su, D. H.; Wang, W. Q.; Chen, X.; Shao, Z. Z. Fabrication of Air-Stable and Conductive Silk Fibroin Gels. ACS Appl. Mater. Interfaces 2018, 10 (44), 38466–38475. https://doi.org/10.1021/acsami.8b14521

Liu, J.; Li, Z.; Lin, Q. R.; Jiang, X. J.; Yao, J. R.; Yang, Y. H.; Shao, Z. Z.; Chen, X. A Robust, Resilient, and Multi-Functional Soy Protein-Based Hydrogel. ACS Sustainable Chem. Eng. 2018, 6 (11), 13730–13738. https://doi.org/10.1021/acssuschemeng.8b01450

Huang, J.; Li, Q.; Shao, Z. Z. Fabricating Highly Luminescent Solid Hybrids Based on Silicon Nanoparticles: A Simple, Versatile and Green Method. Nanoscale 2018, 10 (21), 10250–10255. https://doi.org/10.1039/C8NR00769A

Wen, J.; Yao, J. R.; Chen, X.; Shao, Z. Z. Silk Fibroin Acts as a Self-Emulsifier to Prepare Hierarchically Porous Silk Fibroin Scaffolds through Emulsion-Ice Dual Templates. ACS Omega 2018, 3 (3), 3396–3405. https://doi.org/10.1021/acsomega.7b01874

Yu, D.; Xin, C.; Zhengzhong, S. Preparation and Properties of Antheraea pernyi/Bombyx mori Silk Fibroin Blending Scaffold. Acta Chim. Sin. 2018, 76 (3), 190–195. https://doi.org/10.6023/A17100453

Wang, Y.; Wen, J.; Peng, B.; Hu, B.; Chen, X.; Shao, Z. Z. Understanding the Mechanical Properties and Structure Transition of Antheraea pernyi Silk Fiber Induced by Its Contraction. Biomacromolecules 2018, 19 (6), 1999–2006. https://doi.org/10.1021/acs.biomac.7b01691

Wu, M.; Yang, W. H.; Chen, S. Y.; Yao, J. R.; Shao, Z. Z.; Chen, X. Size-Controllable Dual Drug-Loaded Silk Fibroin Nanospheres through a Facile Formation Process. J. Mater. Chem. B 2018, 6 (8), 1179–1186. https://doi.org/10.1039/C7TB02943H

Li, Z.; Peng, H.; Liu, J.; Tian, Y.; Yang, W. H.; Yao, J. R.; Shao, Z. Z.; Chen, X. Plant Protein-Directed Synthesis of Luminescent Gold Nanocluster Hybrids for Tumor Imaging. ACS Appl. Mater. Interfaces 2018, 10 (1), 83–90. https://doi.org/10.1021/acsami.7b14942

Han, Y.; Ling, S. J.; Qi, Z. M.; Shao, Z. Z.; Chen, X. Application of Far-Infrared Spectroscopy to the Structural Identification of Protein Materials. Phys. Chem. Chem. Phys. 2018, 20 (17), 11643–11648. https://doi.org/10.1039/C8CP00802G

Zheng, K.; Zhong, J. J.; Qi, Z. M.; Ling, S. J.; Kaplan, D. L. Isolation of Silk Mesostructures for Electronic and Environmental Applications. Adv. Funct. Mater. 2018, 28 (51), 1806380. https://doi.org/10.1002/adfm.201806380

Zhang, W. W.; Ye, C.; Zheng, K.; Zhong, J. J.; Tang, Y. Z.; Fan, Y. M.; Buehler, M. J.; Ling, S. J.; Kaplan, D. L. Tensan Silk-Inspired Hierarchical Fibers for Smart Textile Applications. ACS Nano 2018, 12 (7), 6968–6977. https://doi.org/10.1021/acsnano.8b02430

Yeo, J.; Jung, G. S.; Martin-Martinez, F. J.; Ling, S. J.; Gu, G. X.; Qin, Z.; Buehler, M. J. Materials-by-Design: Computation, Synthesis, and Characterization from Atoms to Structures. Phys. Scr. 2018, 93 (5), 053003. https://doi.org/10.1088/1402-4896/aab4e2

Wang, Y.; Guo, J.; Zhou, L.; Ye, C.; Omenetto, F. G.; Kaplan, D. L.; Ling, S. J. Design, Fabrication, and Function of Silk-Based Nanomaterials. Adv. Funct. Mater. 2018, 28 (52), 1805305. https://doi.org/10.1002/adfm.201805305

Ling, S. J.; Kaplan, D. L.; Buehler, M. J. Nanofibrils in Nature and Materials Engineering. Nat. Rev. Mater. 2018, 3 (4), 18016. https://doi.org/10.1038/natrevmats.2018.16

Ling, S. J.; Wang, Q.; Zhang, D.; Zhang, Y. Y.; Mu, X.; Kaplan, D. L.; Buehler, M. J. Integration of Stiff Graphene and Tough Silk for the Design and Fabrication of Versatile Electronic Materials. Adv. Funct. Mater. 2018, 28 (9), 1705291. https://doi.org/10.1002/adfm.201705291

Ling, S. J.; Jin, K.; Qin, Z.; Li, C.; Zheng, K.; Zhao, Y.; Wang, Q.; Kaplan, D. L.; Buehler, M. J. Combining In Silico Design and Biomimetic Assembly: A New Approach for Developing High-Performance Dynamic Responsive Bio-Nanomaterials. Adv. Mater. 2018, 30 (43), e1802306. https://doi.org/10.1002/adma.201802306

Ling, S. J.; Chen, W. S.; Fan, Y. M.; Zheng, K.; Jin, K.; Yu, H. P.; Buehler, M. J.; Kaplan, D. L. Biopolymer Nanofibrils: Structure, Modeling, Preparation, and Applications. Prog. Polym. Sci. 2018, 85, 1–56. https://doi.org/10.1016/j.progpolymsci.2018.06.004

Huang, W.; Ling, S. J.; Li, C.; Omenetto, F. G.; Kaplan, D. L. Silkworm Silk-Based Materials and Devices Generated Using Bio-Nanotechnology. Chem. Soc. Rev. 2018, 47 (17), 6486–6504. https://doi.org/10.1039/C8CS00187A

Guo, J.; Ling, S. J.; Li, W.; Chen, Y.; Li, C.; Omenetto, F. G.; Kaplan, D. L. Coding Cell Micropatterns through Peptide Inkjet Printing for Arbitrary Biomineralized Architectures. Adv. Funct. Mater. 2018, 28 (19), 1800228. https://doi.org/10.1002/adfm.201800228

Zhu, Z.; Ling, S. J.; Yeo, J.; Zhao, S.; Tozzi, L.; Buehler, M. J.; Omenetto, F.; Li, C.; Kaplan, D. L. High-Strength, Durable All-Silk Fibroin Hydrogels with Versatile Processability toward Multifunctional Applications. Adv. Funct. Mater. 2018, 28 (10), 1704757. https://doi.org/10.1002/adfm.201704757

Zhou, W.; Chen, Y.; Roh, T.; Lin, Y.; Ling, S. J.; Zhao, S.; Lin, J. D.; Khalil, N.; Cairns, D. M.; Manousiouthakis, E.; Tse, M.; Kaplan, D. L. Multifunctional Bioreactor System for Human Intestine Tissues. ACS Biomater. Sci. Eng. 2018, 4 (1), 231–239. https://doi.org/10.1021/acsbiomaterials.7b00794

Dinjaski, N.; Ebrahimi, D.; Qin, Z.; Giordano, J. E. M.; Ling, S. J.; Buehler, M. J.; Kaplan, D. L. Predicting Rates of in Vivo Degradation of Recombinant Spider Silk Proteins. J. Tissue Eng. Regen. Med. 2018, 12 (1), e97–e105. https://doi.org/10.1002/term.2380

2017

Fang, G. Q.; Tang, Y. Z.; Qi, Z. M.; Yao, J. R.; Shao, Z. Z.; Chen, X. Precise Correlation of Macroscopic Mechanical Properties and Microscopic Structures of Animal Silks—Using Antheraea pernyi Silkworm Silk as an Example. J. Mater. Chem. B 2017, 5 (30), 6042–6048. https://doi.org/10.1039/C7TB01638G

Zhao, F.; Guo, H.; Zhang, Z.; Ye, J.; Liu, L.; Zhao, C.-X.; Shao, Z. Z. Conformation and Self-Assembly Changes of Isomeric Peptide Amphiphiles Influenced by Switching Tyrosine in the Sequences. J. Mater. Chem. B 2017, 5 (26), 5189–5195. https://doi.org/10.1039/C7TB00736A

Su, D. H.; Yao, M.; Liu, J.; Zhong, Y. M.; Chen, X.; Shao, Z. Z. Enhancing Mechanical Properties of Silk Fibroin Hydrogel through Restricting the Growth of β-Sheet Domains. ACS Appl. Mater. Interfaces 2017, 9 (20), 17489–17498. https://doi.org/10.1021/acsami.7b04623

Li, Z.; Yang, Y. H.; Yao, J. R.; Shao, Z. Z.; Chen, X. A Facile Fabrication of Silk/MoS₂ Hybrids for Photothermal Therapy. Mater. Sci. Eng., C 2017, 79, 123–129. https://doi.org/10.1016/j.msec.2017.05.010

Liu, J.; Su, D. H.; Yao, J. R.; Huang, Y. F.; Shao, Z. Z.; Chen, X. Soy Protein-Based Polyethylenimine Hydrogel and Its High Selectivity for Copper Ion Removal in Wastewater Treatment. J. Mater. Chem. A 2017, 5 (8), 4163–4171. https://doi.org/10.1039/C6TA10814H

Ling, S. J.; Qin, Z.; Li, C.; Huang, W.; Kaplan, D. L.; Buehler, M. J. Polymorphic Regenerated Silk Fibers Assembled through Bioinspired Spinning. Nat. Commun. 2017, 8 (1), 1387. https://doi.org/10.1038/s41467-017-00613-5

Ling, S. J.; Qin, Z.; Huang, W.; Cao, S.; Kaplan, D. L.; Buehler, M. J. Design and Function of Biomimetic Multilayer Water Purification Membranes. Sci. Adv. 2017, 3 (4), e1601939. https://doi.org/10.1126/sciadv.1601939

Jacobsen, M. M.; Tokareva, O. S.; Ebrahimi, D.; Huang, W.; Ling, S. J.; Dinjaski, N.; Li, D.; Simon, M.; Staii, C.; Buehler, M. J.; Kaplan, D. L.; Wong, J. Y. Effect of Terminal Modification on the Molecular Assembly and Mechanical Properties of Protein-Based Block Copolymers. Macromol. Biosci. 2017, 17 (9), 1700095. https://doi.org/10.1002/mabi.201700095

Guo, J.; Li, C.; Ling, S. J.; Huang, W.; Chen, Y.; Kaplan, D. L. Multiscale Design and Synthesis of Biomimetic Gradient Protein/Biosilica Composites for Interfacial Tissue Engineering. Biomaterials 2017, 145, 44–55. https://doi.org/10.1016/j.biomaterials.2017.08.025

Dinjaski, N.; Ebrahimi, D.; Ling, S. J.; Shah, S.; Buehler, M. J.; Kaplan, D. L. Integrated Modeling and Experimental Approaches to Control Silica Modification of Design Silk-Based Biomaterials. ACS Biomater. Sci. Eng. 2017, 3 (11), 2877–2888. https://doi.org/10.1021/acsbiomaterials.6b00236

Chen, C.-T.; Martin-Martinez, F. J.; Ling, S. J.; Qin, Z.; Buehler, M. J. Nacre-Inspired Design of Graphene Oxide-Polydopamine Nanocomposites for Enhanced Mechanical Properties and Multi-Functionalities. Nano Futures 2017, 1 (1), 011003. https://doi.org/10.1088/2399-1984/aa6aed

2016

Luo, K.; Yang, Y. H.; Shao, Z. Z. Physically Crosslinked Biocompatible Silk-Fibroin-Based Hydrogels with High Mechanical Performance. Adv. Funct. Mater. 2016, 26 (6), 872–880. https://doi.org/10.1002/adfm.201503450

Mi, R. X.; Liu, Y. X.; Chen, X.; Shao, Z. Z. Structure and Properties of Various Hybrids Fabricated by Silk Nanofibrils and Nanohydroxyapatite. Nanoscale 2016, 8 (48), 20096–20102. https://doi.org/10.1039/C6NR07913G

Cao, H.; Yang, Y. H.; Chen, X.; Shao, Z. Z. Intelligent Janus Nanoparticles for Intracellular Real-Time Monitoring of Dual Drug Release. Nanoscale 2016, 8 (12), 6754–6760. https://doi.org/10.1039/C6NR00987E

Wang, Y. X.; Ma, R. L.; Hu, K. S.; Kim, S. H.; Fang, G. Q.; Shao, Z. Z.; Tsukruk, V. V. Dramatic Enhancement of Graphene Oxide/Silk Nanocomposite Membranes: Increasing Toughness, Strength, and Young's Modulus via Annealing of Interfacial Structures. ACS Appl. Mater. Interfaces 2016, 8 (37), 24962–24973. https://doi.org/10.1021/acsami.6b08610

Su, D. H.; Jiang, L. B.; Chen, X.; Dong, J.; Shao, Z. Z. Enhancing the Gelation and Bioactivity of Injectable Silk Fibroin Hydrogel with Laponite Nanoplatelets. ACS Appl. Mater. Interfaces 2016, 8 (15), 9619–9628. https://doi.org/10.1021/acsami.6b01891

Yang, W. H.; Shao, Z. Z.; Chen, X. Silk Protein Nanospheres for Paclitaxel/Doxorubicin Synergistic Drug Delivery. Nanomedicine 2016, 12 (2), 554. https://doi.org/10.1016/j.nano.2015.12.178

Wang, S. H.; Cao, H.; Shao, Z. Z. Hydrophilic Aminoclay-Curcumin Nanohybrids for Enhanced Chemotherapy. Nanomedicine 2016, 12 (2), 512. https://doi.org/10.1016/j.nano.2015.12.136

Cao, H.; Yang, Y. H.; Shao, Z. Z. Bimodal Real-Time Monitoring and Dual Responsive Drug Release Based on Janus Mesoporous Silica-Au Nanoparticles. Nanomedicine 2016, 12 (2), 484. https://doi.org/10.1016/j.nano.2015.12.108

Li, Z.; Zheng, Z.; Yang, Y. H.; Fang, G. Q.; Yao, J. R.; Shao, Z. Z.; Chen, X. Robust Protein Hydrogels from Silkworm Silk. ACS Sustainable Chem. Eng. 2016, 4 (3), 1500–1506. https://doi.org/10.1021/acssuschemeng.5b01463

Wang, S. H.; Cao, H.; Zhong, Y. M.; Yang, Y. H.; Shao, Z. Z. A Novel Aminoclay-Curcumin Hybrid for Enhanced Chemotherapy. J. Mater. Chem. B 2016, 4 (24), 4295–4301. https://doi.org/10.1039/C6TB00420B

Ling, S. J.; Liang, H. Y.; Li, Z.; Ma, L.; Yao, J. R.; Shao, Z. Z.; Chen, X. Soy Protein-Directed One-Pot Synthesis of Gold Nanomaterials and Their Functional Conductive Devices. J. Mater. Chem. B 2016, 4 (21), 3643–3650. https://doi.org/10.1039/C6TB00681G

Fang, G. Q.; Sapru, S.; Behera, S.; Yao, J. R.; Shao, Z. Z.; Kundu, S. C.; Chen, X. Exploration of the Tight Structural-Mechanical Relationship in Mulberry and Non-Mulberry Silkworm Silks. J. Mater. Chem. B 2016, 4 (24), 4337–4347. https://doi.org/10.1039/C6TB01049K

Lu, S.; Yang, Y. H.; Yao, J. R.; Shao, Z. Z.; Chen, X. Exploration of the Nature of a Unique Natural Polymer-Based Thermosensitive Hydrogel. Soft Matter 2016, 12 (2), 492–499. https://doi.org/10.1039/C5SM01641J

Zhang, Z. D.; Liu, Y. X.; Chen, X.; Shao, Z. Z. Multi-Responsive Polyethylene-Polyamine/Gelatin Hydrogel Induced by Non-Covalent Interactions. RSC Adv. 2016, 6 (54), 48661–48665. https://doi.org/10.1039/C6RA06356F

Jiang, X. J.; Li, Z.; Yao, J. R.; Shao, Z. Z.; Chen, X. One-Step Synthesis of Soy Protein/Graphene Nanocomposites and Their Application in Photothermal Therapy. Mater. Sci. Eng., C 2016, 68, 798–804. https://doi.org/10.1016/j.msec.2016.07.034

Fang, G. Q.; Yang, Y. H.; Yao, J. R.; Shao, Z. Z.; Chen, X. Formation of Different Gold Nanostructures by Silk Nanofibrils. Mater. Sci. Eng., C 2016, 64, 376–382. https://doi.org/10.1016/j.msec.2016.03.084

Liu, W.; Wang, Y.; Yao, J. R.; Shao, Z. Z.; Chen, X. Tamoxifen-Loaded Silk Fibroin Electrospun Fibers. Mater. Lett. 2016, 178, 31–34. https://doi.org/10.1016/j.matlet.2016.04.177

Zhang, C.; Chen, X.; Shao, Z. Z. Sol-Gel Transition of Regenerated Silk Fibroins in Ionic Liquid/Water Mixtures. ACS Biomater. Sci. Eng. 2016, 2 (1), 12–18. https://doi.org/10.1021/acsbiomaterials.5b00149

Fang, G. Q.; Huang, Y. F.; Tang, Y. Z.; Qi, Z. M.; Yao, J. R.; Shao, Z. Z.; Chen, X. Insights into Silk Formation Process: Correlation of Mechanical Properties and Structural Evolution during Artificial Spinning of Silk Fibers. ACS Biomater. Sci. Eng. 2016, 2 (11), 1992–2000. https://doi.org/10.1021/acsbiomaterials.6b00392

Zhu, J.; Huang, W.; Zhang, Q.; Ling, S. J.; Chen, Y.; Kaplan, D. L. Aqueous-Based Coaxial Electrospinning of Genetically Engineered Silk Elastin Core-Shell Nanofibers. Materials 2016, 9 (4), 221. https://doi.org/10.3390/ma9040221

Ling, S. J.; Zhang, Q.; Kaplan, D. L.; Omenetto, F.; Buehler, M. J.; Qin, Z. Printing of Stretchable Silk Membranes for Strain Measurements. Lab Chip 2016, 16 (13), 2459–2466. https://doi.org/10.1039/C6LC00519E

Ling, S. J.; Li, C.; Jin, K.; Kaplan, D. L.; Buehler, M. J. Liquid Exfoliated Natural Silk Nanofibrils: Applications in Optical and Electrical Devices. Adv. Mater. 2016, 28 (35), 7783–7790. https://doi.org/10.1002/adma.201601783

Ling, S. J.; Jin, K.; Kaplan, D. L.; Buehler, M. J. Ultrathin Free-Standing Bombyx mori Silk Nanofibril Membranes. Nano Lett. 2016, 16 (6), 3795–3800. https://doi.org/10.1021/acs.nanolett.6b01195

Ling, S. J.; Dinjaski, N.; Ebrahimi, D.; Wong, J. Y.; Kaplan, D. L.; Buehler, M. J. Conformation Transitions of Recombinant Spidroins via Integration of Time-Resolved FTIR Spectroscopy and Molecular Dynamic Simulation. ACS Biomater. Sci. Eng. 2016, 2 (8), 1298–1308. https://doi.org/10.1021/acsbiomaterials.6b00234

Li, C.; Hotz, B.; Ling, S. J.; Guo, J.; Haas, D. S.; Marelli, B.; Omenetto, F. G.; Lin, S. J.; Kaplan, D. L. Regenerated Silk Materials for Functionalized Silk Orthopedic Devices by Mimicking Natural Processing. Biomaterials 2016, 110, 24–33. https://doi.org/10.1016/j.biomaterials.2016.09.014

2015

Shen, W. J.; Luan, J. B.; Cao, L. P.; Sun, J.; Yu, L.; Ding, J. D. Thermogelling Polymer-Platinum(IV) Conjugates for Long-Term Delivery of Cisplatin. Biomacromolecules 2015, 16, 105–115. https://doi.org/10.1021/bm501220a

Wang, S. H.; Xu, T.; Shao, Z. Z. The Stability of Silk Fibroin Nanoparticles Coated with Cationic Polymers in Biological Media. J. Controlled Release 2015, 213, E101. https://doi.org/10.1016/j.jconrel.2015.05.170

Cao, H.; Yang, Y. H.; Shao, Z. Z. Doxorubicin Hydrochloride and Curcumin Loaded Silk Fibroin/Hydroxypropylcellulose Hydrogels for Localized Chemotherapy of Cancer. J. Controlled Release 2015, 213, E39. https://doi.org/10.1016/j.jconrel.2015.05.064

Wang, Y.; Song, Y.; Wang, Y.; Chen, X.; Xia, Y. Y.; Shao, Z. Z. Graphene/Silk Fibroin Based Carbon Nanocomposites for High Performance Supercapacitors. J. Mater. Chem. A 2015, 3 (2), 773–781. https://doi.org/10.1039/C4TA04772A

Wang, S. H.; Xu, T.; Yang, Y. H.; Shao, Z. Z. Colloidal Stability of Silk Fibroin Nanoparticles Coated with Cationic Polymer for Effective Drug Delivery. ACS Appl. Mater. Interfaces 2015, 7 (38), 21254–21262. https://doi.org/10.1021/acsami.5b05335

Ma, L.; Yang, Y. H.; Yao, J. R.; Shao, Z. Z.; Huang, Y. F.; Chen, X. Selective Chemical Modification of Soy Protein for a Tough and Applicable Plant Protein-Based Material. J. Mater. Chem. B 2015, 3 (26), 5241–5248. https://doi.org/10.1039/C5TB00523J

Ling, S. J.; Qi, Z. M.; Shao, Z. Z.; Chen, X. Determination of Phase Behaviour in All Protein Blend Materials with Multivariate FTIR Imaging Technique. J. Mater. Chem. B 2015, 3 (5), 834–839. https://doi.org/10.1039/C4TB01808G

Fang, G. Q.; Zheng, Z.; Yao, J. R.; Chen, M.; Tang, Y. Z.; Zhong, J. J.; Qi, Z. M.; Li, Z.; Shao, Z. Z.; Chen, X. Tough Protein-Carbon Nanotube Hybrid Fibers Comparable to Natural Spider Silks. J. Mater. Chem. B 2015, 3 (19), 3940–3947. https://doi.org/10.1039/C5TB00448A

Lin, G.; Zhong, Y. M.; Zhong, J. J.; Shao, Z. Z. Effect of Fe³⁺ on the Silk Fibroin Regulated Direct Growth of Nacre-like Aragonite Hybrids. Cryst. Growth Des. 2015, 15 (12), 5774–5780. https://doi.org/10.1021/acs.cgd.5b01078

2014

Ling, S. J.; Li, C. X.; Adamcik, J.; Shao, Z. Z.; Chen, X.; Mezzenga, R. Modulating Materials by Orthogonally Oriented β-Strands: Composites of Amyloid and Silk Fibroin Fibrils. Adv. Mater. 2014, 26 (26), 4569–4574. https://doi.org/10.1002/adma.201400484

Tian, Y.; Jiang, X. J.; Chen, X.; Shao, Z. Z.; Yang, W. H. Doxorubicin-Loaded Magnetic Silk Fibroin Nanoparticles for Targeted Therapy of Multidrug-Resistant Cancer. Adv. Mater. 2014, 26 (43), 7393–7398. https://doi.org/10.1002/adma.201403562

Fei, X.; Li, W.; Shao, Z. Z.; Seeger, S.; Zhao, D.; Chen, X. Protein Biomineralized Nanoporous Inorganic Mesocrystals with Tunable Hierarchical Nanostructures. J. Am. Chem. Soc. 2014, 136 (44), 15781–15786. https://doi.org/10.1021/ja509334x

Guo, H.; Zhang, J.; Porter, D.; Peng, H.; Löwik, D. W. P. M.; Wang, Y.; Zhang, Z.; Chen, X.; Shao, Z. Z. Ultrafast and Reversible Thermochromism of a Conjugated Polymer Material Based on the Assembly of Peptide Amphiphiles. Chem. Sci. 2014, 5 (11), 4189–4195. https://doi.org/10.1039/C4SC00849A

Ling, S. J.; Li, C. X.; Adamcik, J.; Wang, S. H.; Shao, Z. Z.; Chen, X.; Mezzenga, R. Directed Growth of Silk Nanofibrils on Graphene and Their Hybrid Nanocomposites. ACS Macro Lett. 2014, 3 (2), 146–152. https://doi.org/10.1021/mz400639y

Xu, T.; Liu, W.; Wang, S. H.; Shao, Z. Z. Elucidating the Role of Free Polycationic Chains in Polycation Gene Carriers by Free Chains of Polyethylenimine or N,N,N-Trimethyl Chitosan Plus a Certain Polyplex. Int. J. Nanomed. 2014, 9, 3231–3245. https://doi.org/10.2147/IJN.S63595

Ling, S. J.; Qi, Z. M.; Watts, B.; Shao, Z. Z.; Chen, X. Structural Determination of Protein-Based Polymer Blends with a Promising Tool: Combination of FTIR and STXM Spectroscopic Imaging. Phys. Chem. Chem. Phys. 2014, 16 (17), 7741–7748. https://doi.org/10.1039/C4CP00556B

Xu, T.; Wang, S. H.; Shao, Z. Z. Insight into Polycation Chain Length Affecting Transfection Efficiency by O-Methyl-Free N,N,N-Trimethyl Chitosans as Gene Carriers. Pharm. Res. 2014, 31 (4), 895–907. https://doi.org/10.1007/s11095-013-1210-1

Wang, Y.; Guan, J.; Hawkins, N.; Porter, D.; Shao, Z. Z. Understanding the Variability of Properties in Antheraea pernyi Silk Fibres. Soft Matter 2014, 10 (33), 6321–6331. https://doi.org/10.1039/C4SM01172D

Hao, W.; Porter, D.; Wang, X.; Shao, Z. Z. Silk Fibroin-Mediated Biomineralization of Calcium Carbonate at the Air/Water Interface. CrystEngComm 2014, 16 (39), 9176–9184. https://doi.org/10.1039/C4CE01242A

Liu, Y.; Ling, S. J.; Wang, S. H.; Chen, X.; Shao, Z. Z. Thixotropic Silk Nanofibril-Based Hydrogel with Extracellular Matrix-like Structure. Biomater. Sci. 2014, 2 (10), 1338–1342. https://doi.org/10.1039/C4BM00214H

Yu, S.; Yang, W. H.; Chen, S. Y.; Chen, M.; Liu, Y.; Shao, Z. Z.; Chen, X. Floxuridine-Loaded Silk Fibroin Nanospheres. RSC Adv. 2014, 4 (35), 18171. https://doi.org/10.1039/C4RA02012J

Hao, W.; Porter, D.; Shao, Z. Z. Influences of Film Thickness and Fabrication Method on the Surface Structure and Mineralization-Templating of Silk Fibroin. RSC Adv. 2014, 4 (66), 35258–35262. https://doi.org/10.1039/C4RA04791E

Yin, J.; Duan, Y.; Shao, Z. Z. UV Induced Superhydrophilicity of RSF Film. Acta Chim. Sin. 2014, 72 (1), 51–55. https://doi.org/10.6023/A13090974

Hao, W.; Shao, Z. Z. Superhydrophobic and Highly Oleophobic Nylon Surface. Acta Chim. Sin. 2014, 72 (9), 1023–1028. https://doi.org/10.6023/A14050387

2013

Li, Q.; He, Y.; Chang, J.; Wang, L.; Chen, H.; Tan, Y.-W.; Wang, H.; Shao, Z. Z. Surface-Modified Silicon Nanoparticles with Ultrabright Photoluminescence and Single-Exponential Decay for Nanoscale Fluorescence Lifetime Imaging of Temperature. J. Am. Chem. Soc. 2013, 135 (40), 14924–14927. https://doi.org/10.1021/ja407521p

Fei, X.; Shao, Z. Z.; Chen, X. Synthesis of Hierarchical Three-Dimensional Copper Oxide Nanostructures through a Biomineralization-Inspired Approach. Nanoscale 2013, 5 (17), 7991–7997. https://doi.org/10.1039/C3NR01872E

Wang, Y.; Porter, D.; Shao, Z. Z. Using Solvents with Different Molecular Sizes to Investigate the Structure of Antheraea pernyi Silk. Biomacromolecules 2013, 14 (11), 3936–3942. https://doi.org/10.1021/bm401056x

Wang, Q.; Chen, Q. Y.; Yang, Y. H.; Shao, Z. Z. Effect of Various Dissolution Systems on the Molecular Weight of Regenerated Silk Fibroin. Biomacromolecules 2013, 14 (1), 285–289. https://doi.org/10.1021/bm301741q

Guo, H.; Zhang, J.; Xu, T.; Zhang, Z.; Yao, J. R.; Shao, Z. Z. The Robust Hydrogel Hierarchically Assembled from a pH Sensitive Peptide Amphiphile Based on Silk Fibroin. Biomacromolecules 2013, 14 (8), 2733–2738. https://doi.org/10.1021/bm400531d

Fei, X.; Jia, M.; Du, X.; Yang, Y. H.; Zhang, R.; Shao, Z. Z.; Zhao, X.; Chen, X. Green Synthesis of Silk Fibroin-Silver Nanoparticle Composites with Effective Antibacterial and Biofilm-Disrupting Properties. Biomacromolecules 2013, 14 (12), 4483–4488. https://doi.org/10.1021/bm401357v

Ma, L.; Yang, Y. H.; Yao, J. R.; Shao, Z. Z.; Chen, X. Robust Soy Protein Films Obtained by Slight Chemical Modification of Polypeptide Chains. Polym. Chem. 2013, 4 (21), 5425. https://doi.org/10.1039/C3PY00557G

Ling, S. J.; Qi, Z. M.; Knight, D. P.; Shao, Z. Z.; Chen, X. FTIR Imaging, a Useful Method for Studying the Compatibility of Silk Fibroin-Based Polymer Blends. Polym. Chem. 2013, 4 (21), 5401–5406. https://doi.org/10.1039/C3PY00508A

Ling, S. J.; Qi, Z. M.; Knight, D. P.; Huang, Y. F.; Huang, L.; Zhou, H.; Shao, Z. Z.; Chen, X. Insight into the Structure of Single Antheraea pernyi Silkworm Fibers Using Synchrotron FTIR Microspectroscopy. Biomacromolecules 2013, 14 (6), 1885–1892. https://doi.org/10.1021/bm400267m

凌盛杰; 黄郁芳; 黄蕾; 邵正中; 陈新. 同步辐射红外显微光谱学和成像技术在分析化学中的应用. 化学进展 2013, 25 (5), 821–831. https://doi.org/10.7536/PC121040

Hao, R.; Zhang, J.; Xu, T.; Huang, L.; Yao, J. R.; Chen, X.; Shao, Z. Z. Characterization and Assembly Investigation of a Dodecapeptide Hydrolyzed from the Crystalline Domain of Bombyx mori Silk Fibroin. Polym. Chem. 2013, 4 (10), 3005–3011. https://doi.org/10.1039/C3PY21096K

Zhou, L.; Wang, Q.; Wen, J.; Chen, X.; Shao, Z. Z. Preparation and Characterization of Transparent Silk Fibroin/Cellulose Blend Films. Polymer 2013, 54 (18), 5035–5042. https://doi.org/10.1016/j.polymer.2013.07.002

Cao, H.; Lin, G.; Yao, J. R.; Shao, Z. Z. Amphiphilic Polypeptides as a Bifunctional Template in the Mineralization of Calcium Carbonate at the Air/Water Interface. Macromol. Biosci. 2013, 13 (5), 650–659. https://doi.org/10.1002/mabi.201200334

Liang, M.; Yao, J. R.; Chen, X.; Huang, L.; Shao, Z. Z. Silk Fibroin Immobilization on Poly(ethylene terephthalate) Films: Comparison of Two Surface Modification Methods and Their Effect on Mesenchymal Stem Cells Culture. Mater. Sci. Eng., C 2013, 33 (3), 1409–1416. https://doi.org/10.1016/j.msec.2012.12.069

Cao, Z.; Wen, J.; Yao, J. R.; Chen, X.; Ni, Y.; Shao, Z. Z. Facile Fabrication of the Porous Three-Dimensional Regenerated Silk Fibroin Scaffolds. Mater. Sci. Eng., C 2013, 33 (6), 3522–3529. https://doi.org/10.1016/j.msec.2013.04.045

Zhao, S.; Yao, J. R.; Fei, X.; Shao, Z. Z.; Chen, X. An Antimicrobial Film by Embedding in Situ Synthesized Silver Nanoparticles in Soy Protein Isolate. Mater. Lett. 2013, 95, 142–144. https://doi.org/10.1016/j.matlet.2013.01.014

Cao, H.; Yao, J. R.; Shao, Z. Z. Fabrication of Superhydrophobic Surfaces via CaCO₃ Mineralization Mediated by Poly(glutamic acid). J. Solid State Chem. 2013, 199, 338–343. https://doi.org/10.1016/j.jssc.2012.12.024

Cao, H.; Chen, X.; Yao, J. R.; Shao, Z. Z. Fabrication of an Alternative Regenerated Silk Fibroin Nanofiber and Carbonated Hydroxyapatite Multilayered Composite via Layer-by-Layer. J. Mater. Sci. 2013, 48 (1), 150–155. https://doi.org/10.1007/s10853-012-6722-6

2012

Wang, T.; Porter, D.; Shao, Z. Z. The Intrinsic Ability of Silk Fibroin to Direct the Formation of Diverse Aragonite Aggregates. Adv. Funct. Mater. 2012, 22 (2), 435–441. https://doi.org/10.1002/adfm.201101011

Liu, Y.; Wu, Z.; Chen, X.; Shao, Z. Z.; Wang, H.; Zhao, D. A Hierarchical Adsorption Material by Incorporating Mesoporous Carbon into Macroporous Chitosan Membranes. J. Mater. Chem. 2012, 22 (24), 11908. https://doi.org/10.1039/C2JM31338C

Wang, Q.; Yang, Y. H.; Chen, X.; Shao, Z. Z. Investigation of Rheological Properties and Conformation of Silk Fibroin in the Solution of AmimCl. Biomacromolecules 2012, 13 (6), 1875–1881. https://doi.org/10.1021/bm300387z

Yang, Y. H.; Dicko, C.; Bain, C. D.; Gong, Z.; Jacobs, R. M. J.; Shao, Z. Z.; Terry, A. E.; Vollrath, F. Behavior of Silk Protein at the Air-Water Interface. Soft Matter 2012, 8 (37), 9705–9712. https://doi.org/10.1039/C2SM26111A

Gong, Z.; Yang, Y. H.; Ren, Q.; Chen, X.; Shao, Z. Z. Injectable Thixotropic Hydrogel Comprising Regenerated Silk Fibroin and Hydroxypropylcellulose. Soft Matter 2012, 8 (10), 2875–2883. https://doi.org/10.1039/C2SM06984A

Zhang, J.; Xu, T.; Yao, J. R.; Huang, L.; Chen, X.; Shao, Z. Z. Quasi One-Dimensional Assembly of Gold Nanoparticles Templated by a pH-Sensitive Peptide Amphiphile from Silk Fibroin. RSC Adv. 2012, 2 (13), 5599–5604. https://doi.org/10.1039/C2RA20507F

Liu, Y.; Feng, Z.; Shao, Z. Z.; Chen, X. Chitosan-Based Membrane Chromatography for Protein Adsorption and Separation. Mater. Sci. Eng., C 2012, 32 (6), 1669–1673. https://doi.org/10.1016/j.msec.2012.04.064

Chen, M.; Shao, Z. Z.; Chen, X. Paclitaxel-Loaded Silk Fibroin Nanospheres. J. Biomed. Mater. Res., Part A 2012, 100 (1), 203–210. https://doi.org/10.1002/jbm.a.33265

Ling, S. J.; Zhou, L.; Zhou, W.; Shao, Z. Z.; Chen, X. Conformation Transition Kinetics and Spinnability of Regenerated Silk Fibroin with Glycol, Glycerol and Polyethylene Glycol. Mater. Lett. 2012, 81, 13–15. https://doi.org/10.1016/j.matlet.2012.04.136

Cao, H.; Yao, J. R.; Shao, Z. Z. Synthesis of Poly(γ-benzyl-L-glutamate) with Well-Defined Terminal Structures and Its Block Polypeptides with Alanine, Leucine and Phenylalanine. Polym. Int. 2012, 61 (5), 774–779. https://doi.org/10.1002/pi.4150

Chen, X.; Cai, H.; Ling, S. J.; Shao, Z. Z.; Huang, Y. F. Conformation Transition of Bombyx mori Silk Protein Monitored by Time-Dependent Fourier Transform Infrared (FT-IR) Spectroscopy: Effect of Organic Solvent. Appl. Spectrosc. 2012, 66 (6), 696–699. https://doi.org/10.1366/11-06551

Tian, K.; Shao, Z. Z.; Chen, X. Investigation on Thermally-Induced Conformation Transition of Soy Protein Film with Variable-Temperature FTIR Spectroscopy. J. Appl. Polym. Sci. 2012, 124 (4), 2838–2845. https://doi.org/10.1002/app.34949

Yang, F.; Yao, J. R.; Chen, X.; Shao, Z. Z. Preparation and Antimicrobial Properties of PVA/Tannin Blend Films. Acta Polym. Sin. 2012, (2), 125–130. https://doi.org/10.3724/SP.J.1105.2012.11162

2011

Ling, S. J.; Qi, Z. M.; Knight, D. P.; Shao, Z. Z.; Chen, X. Synchrotron FTIR Microspectroscopy of Single Natural Silk Fibers. Biomacromolecules 2011, 12 (9), 3344–3349. https://doi.org/10.1021/bm2006032

Fu, C. J.; Porter, D.; Chen, X.; Vollrath, F.; Shao, Z. Z. Understanding the Mechanical Properties of Antheraea pernyi Silk—From Primary Structure to Condensed Structure of the Protein. Adv. Funct. Mater. 2011, 21 (4), 729–737. https://doi.org/10.1002/adfm.201001046

Zhang, J.; Hao, R.; Huang, L.; Yao, J. R.; Chen, X.; Shao, Z. Z. Self-Assembly of a Peptide Amphiphile Based on Hydrolysed Bombyx mori Silk Fibroin. Chem. Commun. 2011, 47 (37), 10296–10298. https://doi.org/10.1039/C1CC12633D

Wang, T.; Che, R.; Li, W.; Mi, R. X.; Shao, Z. Z. Control over Different Crystallization Stages of CaCO₃ Mediated by Silk Fibroin. Cryst. Growth Des. 2011, 11 (6), 2164–2171. https://doi.org/10.1021/cg101410u

Wu, Y.; Cheng, C.; Yao, J. R.; Chen, X.; Shao, Z. Z. Crystallization of Calcium Carbonate on Chitosan Substrates in the Presence of Regenerated Silk Fibroin. Langmuir 2011, 27 (6), 2804–2810. https://doi.org/10.1021/la104712h

Ruan, Y.; Lin, H.; Yao, J. R.; Chen, Z. C.; Shao, Z. Z. Preparation of 3D Fibroin/Chitosan Blend Porous Scaffold for Tissue Engineering via a Simplified Method. Macromol. Biosci. 2011, 11 (3), 419–426. https://doi.org/10.1002/mabi.201000389

Qiu, X.; Yang, Y. H.; Wang, L.; Lu, S.; Shao, Z. Z.; Chen, X. Synergistic Interactions during Thermosensitive Chitosan-β-Glycerophosphate Hydrogel Formation. RSC Adv. 2011, 1 (2), 282–289. https://doi.org/10.1039/C1RA00149C

Chen, M.; Yao, J. R.; Shao, Z. Z.; Chen, X. Biomacromolecule-Based Nanoparticle Drug Carriers. Prog. Chem. 2011, 23 (1), 202–212. https://doi.org/10.7536/PC100932

Yuan, Q.; Yao, J. R.; Shao, Z. Z. Improving the Mechanical Properties of Silk Fiber/Fibroin Composites by Interfacial Modification. Acta Polym. Sin. 2011, (11), 1329–1335. https://doi.org/10.3724/SP.J.1105.2011.11003

Wen, J.; Yao, J. R.; Shao, Z. Z. Recent Progress and Application of Non-Bioactive Proteins in Material Fields. Acta Polym. Sin. 2011, (1), 12–23. https://doi.org/10.3724/SP.J.1105.2011.10223

2010

Leng, B.; Shao, Z. Z.; Bomans, P. H. H.; Brylka, L. J.; Sommerdijk, N. A. J. M.; de With, G.; Ming, W. Cryogenic Electron Tomography Reveals the Template Effect of Chitosan in Biomimetic Silicification. Chem. Commun. 2010, 46 (10), 1703–1705. https://doi.org/10.1039/B920070J

Yin, J.; Chen, E.; Porter, D.; Shao, Z. Z. Enhancing the Toughness of Regenerated Silk Fibroin Film through Uniaxial Extension. Biomacromolecules 2010, 11 (11), 2890–2895. https://doi.org/10.1021/bm100643q

Wang, T.; Leng, B.; Che, R.; Shao, Z. Z. Biomimetic Synthesis of Multilayered Aragonite Aggregates Using Alginate as Crystal Growth Modifier. Langmuir 2010, 26 (16), 13385–13392. https://doi.org/10.1021/la101671k

Gong, Z.; Yang, Y. H.; Huang, L.; Chen, X.; Shao, Z. Z. Formation Kinetics and Fractal Characteristics of Regenerated Silk Fibroin Alcogel Developed from Nanofibrillar Network. Soft Matter 2010, 6 (6), 1217–1223. https://doi.org/10.1039/B913510C

Yuan, Q.; Yao, J. R.; Huang, L.; Chen, X.; Shao, Z. Z. Correlation between Structural and Dynamic Mechanical Transitions of Regenerated Silk Fibroin. Polymer 2010, 51 (26), 6278–6283. https://doi.org/10.1016/j.polymer.2010.10.019

Yuan, Q.; Yao, J. R.; Chen, X.; Huang, L.; Shao, Z. Z. The Preparation of High Performance Silk Fiber/Fibroin Composite. Polymer 2010, 51 (21), 4843–4849. https://doi.org/10.1016/j.polymer.2010.08.056

Tian, K.; Porter, D.; Yao, J. R.; Shao, Z. Z.; Chen, X. Kinetics of Thermally-Induced Conformational Transitions in Soybean Protein Films. Polymer 2010, 51 (11), 2410–2416. https://doi.org/10.1016/j.polymer.2010.03.049

Leng, B.; Jiang, F.; Lu, K.; Ming, W.; Shao, Z. Z. Growth of Calcium Carbonate Mediated by Slowly Released Alginate. CrystEngComm 2010, 12 (3), 730–736. https://doi.org/10.1039/B918225K

Guan, J.; Porter, D.; Tian, K.; Shao, Z. Z.; Chen, X. Morphology and Mechanical Properties of Soy Protein Scaffolds Made by Directional Freezing. J. Appl. Polym. Sci. 2010, 118 (3), 1658–1665. https://doi.org/10.1002/app.32579

Jiang, X. J.; Guan, J.; Chen, X.; Shao, Z. Z. Preparation of Regenerated Silk Fibroin Directional Scaffolds. Acta Chim. Sin. 2010, 68 (18), 1909–1914. https://doi.org/10.6023/A1002283

2009

Zhou, G. Q.; Shao, Z. Z.; Knight, D. P.; Yan, J. P.; Chen, X. Silk Fibers Extruded Artificially from Aqueous Solutions of Regenerated Bombyx mori Silk Fibroin are Tougher than Their Natural Counterparts. Adv. Mater. 2009, 21 (3), 366–370. https://doi.org/10.1002/adma.200800582

Gong, Z.; Huang, L.; Yang, Y. H.; Chen, X.; Shao, Z. Z. Two Distinct β-Sheet Fibrils from Silk Protein. Chem. Commun. 2009, (48), 7506–7508. https://doi.org/10.1039/B914218E

Fu, C. J.; Shao, Z. Z.; Fritz, V. Animal Silks: Their Structures, Properties and Artificial Production. Chem. Commun. 2009, (43), 6515–6529. https://doi.org/10.1039/B911049F

Mo, C. L.; Holland, C.; Porter, D.; Shao, Z. Z.; Vollrath, F. Concentration State Dependence of the Rheological and Structural Properties of Reconstituted Silk. Biomacromolecules 2009, 10 (10), 2724–2728. https://doi.org/10.1021/bm900452u

Fu, C. J.; Porter, D.; Shao, Z. Z. Moisture Effects on Antheraea pernyi Silk's Mechanical Property. Macromolecules 2009, 42 (20), 7877–7880. https://doi.org/10.1021/ma901321k

Leng, B.; Shao, Z. Z.; de With, G.; Ming, W. Superoleophobic Cotton Textiles. Langmuir 2009, 25 (4), 2456–2460. https://doi.org/10.1021/la8031144

Chen, X.; Knight, D. P.; Shao, Z. Z. β-Turn Formation during the Conformation Transition in Silk Fibroin. Soft Matter 2009, 5 (14), 2777. https://doi.org/10.1039/B900908F

Porter, D.; Vollrath, F.; Tian, K.; Chen, X.; Shao, Z. Z. A Kinetic Model for Thermal Degradation in Polymers with Specific Application to Proteins. Polymer 2009, 50 (7), 1814–1818. https://doi.org/10.1016/j.polymer.2009.02.016

Feng, Z.; Shao, Z. Z.; Yao, J. R.; Huang, Y. F.; Chen, X. Protein Adsorption and Separation with Chitosan-Based Amphoteric Membranes. Polymer 2009, 50 (5), 1257–1263. https://doi.org/10.1016/j.polymer.2009.01.006

Cao, H.; Chen, X.; Huang, L.; Shao, Z. Z. Electrospinning of Reconstituted Silk Fiber from Aqueous Silk Fibroin Solution. Mater. Sci. Eng., C 2009, 29 (7), 2270–2274. https://doi.org/10.1016/j.msec.2009.05.012

Mo, C. L.; Wu, P.; Chen, X.; Shao, Z. Z. The Effect of Water on the Conformation Transition of Bombyx mori Silk Fibroin. Vib. Spectrosc. 2009, 51 (1), 105–109. https://doi.org/10.1016/j.vibspec.2008.11.004

Jiang, F.; Yang, Y. H.; Huang, L.; Chen, X.; Shao, Z. Z. Microspheres of Calcium Carbonate Composite Regulated by Sodium Polyacrylates with Various Ways. J. Appl. Polym. Sci. 2009, 114 (6), 3686–3692. https://doi.org/10.1002/app.31024

Mo, C. L.; Dicko, C.; Shao, Z. Z.; Chen, X. Time-Resolved Total Reflectance FT-IR Spectroscopy Characterization on Conformational Change of Silk Fibroin Induced by Acetic Acid. Acta Chim. Sin. 2009, 67 (22), 2641–2644. https://doi.org/10.6023/A0901222

Zhong, Y. M.; Yang, Y. H.; Chen, X.; Shao, Z. Z. Cu(II)-Induced Conformation Transition of Regenerated Silk Fibroin in Aqueous Solutions. Acta Polym. Sin. 2009, (10), 1056–1061. https://doi.org/10.3724/SP.J.1105.2009.01056

2008

Cheng, C.; Shao, Z. Z.; Vollrath, F. Silk Fibroin-Regulated Crystallization of Calcium Carbonate. Adv. Funct. Mater. 2008, 18 (15), 2172–2179. https://doi.org/10.1002/adfm.200701130

Leng, B.; Chen, X.; Shao, Z. Z.; Ming, W. Biomimetic Synthesis of Silica with Chitosan-Mediated Morphology. Small 2008, 4 (6), 755–758. https://doi.org/10.1002/smll.200700891

Cheng, C.; Yang, Y. H.; Chen, X.; Shao, Z. Z. Templating Effect of Silk Fibers in the Oriented Deposition of Aragonite. Chem. Commun. 2008, (43), 5511–5513. https://doi.org/10.1039/B810337B

Cheng, C.; Shao, Z. Z.; Chen, X. Composite Material Made of Regenerated Silk Fibroin and Silica Sol. Acta Polym. Sin. 2008, (10), 974–978. https://doi.org/10.3724/SP.J.1105.2008.00974

2007

Cao, Z.; Chen, X.; Yao, J. R.; Huang, L.; Shao, Z. Z. The Preparation of Regenerated Silk Fibroin Microspheres. Soft Matter 2007, 3 (7), 910–915. https://doi.org/10.1039/B703139D

2006

Zhou, C.; Leng, B.; Yao, J. R.; Qian, J.; Chen, X.; Zhou, P.; Knight, D. P.; Shao, Z. Z. Synthesis and Characterization of Multiblock Copolymers Based on Spider Dragline Silk Proteins. Biomacromolecules 2006, 7 (8), 2415–2419. https://doi.org/10.1021/bm060199t

Chen, X.; Shao, Z. Z.; Vollrath, F. The Spinning Processes for Spider Silk. Soft Matter 2006, 2 (6), 448–451. https://doi.org/10.1039/B601286H

Mo, C. L.; Wu, P.; Chen, X.; Shao, Z. Z. Near-Infrared Characterization on the Secondary Structure of Regenerated Bombyx mori Silk Fibroin. Appl. Spectrosc. 2006, 60 (12), 1438–1441. https://doi.org/10.1366/000370206779321454

2005

Liu, Y.; Shao, Z. Z.; Vollrath, F. Relationships between Supercontraction and Mechanical Properties of Spider Silk. Nat. Mater. 2005, 4 (12), 901–905. https://doi.org/10.1038/nmat1534

Liu, Y.; Shao, Z. Z.; Vollrath, F. Extended Wet-Spinning Can Modify Spider Silk Properties. Chem. Commun. 2005, (19), 2489–2491. https://doi.org/10.1039/B500319A

2004

Yang, Y. H.; Shao, Z. Z.; Chen, X.; Zhou, P. Optical Spectroscopy to Investigate the Structure of Regenerated Bombyx mori Silk Fibroin in Solution. Biomacromolecules 2004, 5 (3), 773–779. https://doi.org/10.1021/bm0343848

2002

Shao, Z. Z.; Vollrath, F. Materials: Surprising Strength of Silkworm Silk. Nature 2002, 418 (6899), 741. https://doi.org/10.1038/418741a

2001

Vollrath, F.; Madsen, B.; Shao, Z. Z. The Effect of Spinning Conditions on the Mechanics of a Spider's Dragline Silk. Proc. R. Soc. B 2001, 268 (1483), 2339–2346. https://doi.org/10.1098/rspb.2001.1590

Chen, X.; Shao, Z. Z.; Marinkovic, N. S.; Miller, L. M.; Zhou, P.; Chance, M. R. Conformation Transition Kinetics of Regenerated Bombyx mori Silk Fibroin Membrane Monitored by Time-Resolved FTIR Spectroscopy. Biophys. Chem. 2001, 89 (1), 25–34. https://doi.org/10.1016/S0301-4622(00)00213-1